En ontain viruses, Unless you need to edit, it's safer to stay in Protected View. 1. Write the correct IUPAC names for the following orgarnic cormpounds: Br CH3 H3C H. (Assign E or Z configuration) b. 2. Classify the following reagents as either nucleophiles or electrophiles: HS, OH,, CH,COOH, H,SO,
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- 5. Classify the following reagents as either nucleophiles or electrophiles: Zn? CH;NH, , HS , OH; , CH;COOH , H,SO,Item 2 Draw the organic products formed in each reaction. Consider both substitution and elimination products, if possible. Indicate the type of reaction that happened (SN1, SN2, E1, E2). Include stereochemistry and regiochemistry if relevant. For multiple products, identify which is the major and which is th]e minor product. a. b. C. d. e. H₂C 9H **** CH3 CH₂CH3 Br Br CH₂CH C6H5 Br -OC(CH3)3 OC(CH3)3 CH3CH₂OH TOH CH₂OHFor the given SN2 reaction, draw the organic and inorganic products of the reaction, and identify the nucleophile, substrate, and leaving group. Include wedge-and-dash bonds and draw hydrogen on a stereocenter. Hmm.. CEN + CI Organic product Inorganic product
- 10. Draw the structure of the reactant(s) or major organic product(s) of each of the following reactions or write N.R for no reaction. There can be more than one answer per box. Show the correct stereochemistry when needed! J... Brz (2 equiv.) CH₂Cl₂ Nal, acetone (excess) AgNO3, EtOH (excess) Oot NC OH H3PO4 heatDraw the most stable resonance form for the intermediate in the following electrophilic substitution reaction. Ⓒ. CCl₂ • You do not have to consider stereochemistry. . Include all valence lone pairs in your answer. . In cases where there is more than one answer, just draw one. Bo H₂SO4 First stage in synthesis of the insecticide DDT, which is now banned in the US #₂ SAIF CI OH CC135. Classify the following reagents as either nucleophiles or electrophiles: Zn2* , CH3NH2 , HS , OH2 , CH3COOH, H2SO4
- Draw the product(s) of the following reactions. 1. BH₂/THF 2. H₂O₂/ aqueous NaOH H₂C-CEC-H You do not have to consider stereochemistry. Separate multiple products using the + sign from the drop-down menu. • You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material. Mill ? ChemDoodleⓇ n [ ]#Draw the product(s) of the following reactions. CEC-H / • You do not have to consider stereochemistry. • Separate multiple products using the + sign from the drop-down menu. • You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material. ? 1. BH3/THF 2. H₂O₂ / aqueous NaOH ChemDoodle #[ ] در O. √nDraw the structure of the product of this reaction. H CH2CH3 Br H-.. КОН E2 elimination product H-- Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If there are alternative structures, draw the most stable one. • If no reaction occurs, draw the organic starting material.
- keferences Draw the structure(s) of the major organic product(s) of the following reaction. H. PPH3 THE • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, draw both stereoisomers. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Include anionic counter-ions, e.g., I-, in your answer, but draw them in their own sketcher. C opy asteFor the given SN2 reaction, draw the organic and inorganic products of the reaction, and identify the nucleophile, substrate, and leaving group. Include wedge-and-dash bonds and draw hydrogen on a stereocenter. HI.... + CI Draw the organic product. :C=N to H Organic product + Inorganic product Draw the inorganic product. ūBelow is the free energy diagram for the substitution reaction of 2-chlorobutane with hydroxide ion: Reaction coardinate Draw the structures, which correspond to A and C in the free-energy diagram above for the reaction of 2-chlorobutane with hydroxide ion. a. b. Label the free energy of activation (AG#) and free energy change AG") on the diagram above. c. Is the reaction exergonic or endergonic (circle one)? page 4 of 17 Free energy