Based solely on IMF, list the following substances from highest vapor pressure to lowest vapor pressure: CH3CH2OH , CH3CH2Br , CH3CH3 and BaCl2

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter11: Alkanes
Section: Chapter Questions
Problem 11.47P
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Based solely on IMF, list the following substances from highest vapor pressure to lowest vapor pressure: CH3CH2OH , CH3CH2Br , CH3CH3 and BaCl2
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Step 1

The list of the different types of intermolecular forces is as:

Type of IMF Types of species involved
Attractive strength
Ion-Ion Cations and anions only. Very high
Ion-Dipole  Ions and a polar molecule. Stronger
Dipole-Dipole Polar molecules Moderately strong
Dipole-Induced dipole A polar molecule interacting with a non-polar molecule Very weak

Induced dipole-Induced dipole (London Dispersion forces)

Non-polar molecules Very weak

Hydrogen bonding (Dipole-Dipole)

Polar molecules (H of one atom interacts with the electronegative atom of another molecule) Strong
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