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Based on & value of the peaks a, b, c, and d in the figures below, indicate whether the ansitions are spin-forbidden, spin-allowed and Laporte forbidden, or fully allowed ansitions.

Based on & value of the peaks a, b, c, and d in the figures below, indicate whether the ansitions are spin-forbidden, spin-allowed and Laporte forbidden, or fully allowed ansitions.

Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter18: Raman Spectroscopy
Section: Chapter Questions
Problem 18.7QAP
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10. Consider the following spectra: 14 MnO4- COC142- A 10 C at ww 25,000 30,000 Dicm) X(nm) € 2400- 800- B-700 0+ 15.000 500 € 300 100 0.03 D 1600 ㅅ 18 000 21000 24000 Frequency (cm) 0.02 € 0.01 a. Based on & value of the peaks a, b, c, and d in the figures below, indicate whether the transitions are spin-forbidden, spin-allowed and Laporte forbidden, or fully allowed transitions. b. Match each of the following complexes to the respective spectrum (A-D). Mn(H₂O)62+ Co(H,O)62+ Two things to note: A and B have different scales for ɛ. Also note that the x-axis for A and B is in λ (wavelength) and for C and D is in wavenumber (energy).
Transcribed Image Text:10. Consider the following spectra: 14 MnO4- COC142- A 10 C at ww 25,000 30,000 Dicm) X(nm) € 2400- 800- B-700 0+ 15.000 500 € 300 100 0.03 D 1600 ㅅ 18 000 21000 24000 Frequency (cm) 0.02 € 0.01 a. Based on & value of the peaks a, b, c, and d in the figures below, indicate whether the transitions are spin-forbidden, spin-allowed and Laporte forbidden, or fully allowed transitions. b. Match each of the following complexes to the respective spectrum (A-D). Mn(H₂O)62+ Co(H,O)62+ Two things to note: A and B have different scales for ɛ. Also note that the x-axis for A and B is in λ (wavelength) and for C and D is in wavenumber (energy).
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