(b). Urea (NH2CONH2) is the end product in protein metabolism in animals. The decomposition of urea in 0.1 M HCI occurs according to the reaction below. NH₂CONH2 (aq) + H*(aq) + 2H₂O (1)→ 2NH4+ (aq) · + HCO3- (aq) The reaction is first order in urea and first order overall. When [NH₂CONH2] = 0.300M, the rate at 51.05 °C is 7.56 x 10-5. (i). Determine the rate constant, k? (ii). Calculate the concentration of urea in this solution after 4.00 X 10³ s if the starting concentration is 0.400 M. (iii). Calculate the half-life for this reaction at 51.05 °C.
(b). Urea (NH2CONH2) is the end product in protein metabolism in animals. The decomposition of urea in 0.1 M HCI occurs according to the reaction below. NH₂CONH2 (aq) + H*(aq) + 2H₂O (1)→ 2NH4+ (aq) · + HCO3- (aq) The reaction is first order in urea and first order overall. When [NH₂CONH2] = 0.300M, the rate at 51.05 °C is 7.56 x 10-5. (i). Determine the rate constant, k? (ii). Calculate the concentration of urea in this solution after 4.00 X 10³ s if the starting concentration is 0.400 M. (iii). Calculate the half-life for this reaction at 51.05 °C.
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.50QE
Related questions
Question
please answer both question. i will give good rating for you
![(b). Urea (NH2CONH2) is the end product in protein metabolism in animals. The
decomposition of urea in 0.1 M HCI occurs according to the reaction below.
NH₂CONH2 (aq) + H*(aq) + 2H₂O (1)→ 2NH4+ (aq) + HCO3- (aq)
The reaction is first order in urea and first order overall.
When [NH₂CONH2] = 0.300M, the rate at 51.05 °C is 7.56 x 10-5.
(i). Determine the rate constant, k?
(ii).
Calculate the concentration of urea in this solution after 4.00 X 10³ s if
the starting concentration is 0.400 M.
(iii). Calculate the half-life for this reaction at 51.05 °C.
(c). The volume of gas at 25°C and 1.00 bar adsorbed on the surface of 1.75 g of
a sample of silica at 0°C was 1.52 cm³ at 55.4 kPa and 2.67 cm³ at 108 kPa.
Calculate the value of Vmon.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd796ae82-b7a1-4aac-bdc2-618bcc17e432%2F764c19f9-a239-413b-b805-f727d3ee270d%2F2chplp_processed.jpeg&w=3840&q=75)
Transcribed Image Text:(b). Urea (NH2CONH2) is the end product in protein metabolism in animals. The
decomposition of urea in 0.1 M HCI occurs according to the reaction below.
NH₂CONH2 (aq) + H*(aq) + 2H₂O (1)→ 2NH4+ (aq) + HCO3- (aq)
The reaction is first order in urea and first order overall.
When [NH₂CONH2] = 0.300M, the rate at 51.05 °C is 7.56 x 10-5.
(i). Determine the rate constant, k?
(ii).
Calculate the concentration of urea in this solution after 4.00 X 10³ s if
the starting concentration is 0.400 M.
(iii). Calculate the half-life for this reaction at 51.05 °C.
(c). The volume of gas at 25°C and 1.00 bar adsorbed on the surface of 1.75 g of
a sample of silica at 0°C was 1.52 cm³ at 55.4 kPa and 2.67 cm³ at 108 kPa.
Calculate the value of Vmon.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 6 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning