(b) Why is the following not a good way to prepare this ether? CONCISELY explain. (Three sentences max.) OH X". +H3C CH₂. OH H₂SO4 (cat amount) (~120°C)
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- Which of the following aldehydes has the highest solubility in water? A) CH₃CH₂C(=O)H B) CH₃CH₂CH₂CH₂C(=O)H C) CH₃(CH₂)₅C(=O)H D) CH₃(CH₂)₁₀C(=O)H E) All of these have equal solubility.The following reaction can be carried out in two steps. Choose the correct reagents i) and ii) to perform the following reaction. CN Oi) H₂O, acid catalyst; ii) CN Oi) HBr; ii) CNT Oi) CN; ii) H₂O, acid catalyst i) CN; ii) heat i) Br₂; ii) CN .Which of the following would accomplish the transformation below? a) 1. HSCH2CH2SH, H+; 2. H2, Raney Ni b) H2N-NH2, NaOH(aq), heat c) H2, Pd d) All of the above
- 10. E to CH3ONa a) Br₂ Br2 1. Mg /ether khan (A) (B) (C) (D) hv FeBr3 hv 2. CO2 3. H3O+ C1 B2 B3 B1 KMnO4 H+ C1 Mg, ether CHO b) 1. CH3Mgl H2SO4 HBr 1. Mgether khan A B D to 2. H3O+ peroxide 2. H₂C-CH2 ° CH3COCI AICI 3 1. C1 1. 03 G F E 2. H3O+ 2. Na₂S 3. H3O+Q6. Fill in the blanks left in each of the following syntheses: Example: OH di-ar Find the flow(s): OH H₂0⁰ CH₂OH, H OH Mair NHANH, KOH OHIn this time of pandemic, we are very much aware of different disinfectants so as not to be infected by viruses. Alcohols are one of the most common disinfectants as well as phenols. Explain how alcohols and phenols are prepared to be used as disinfectants. Answer in 2-3 sentences only.
- H₂N. Structure 1 ОН H₂N .OH Structure 2 HaN. Reaction Bank: Reaction A: 'N' لز (H3CC" Reaction B: DCCD, HCI Reaction C: CF3CO2H ہ C(CH3)3 OH(b) (c) CH3CH2CH2CH2OH NBS hv, CCl4 ? (d) OH PBг3 ? Ether socl2 ? (e) Mg H₂O CH3CH2CHBгCH3 A? B? Ether (f) Li Cul CH3CH2CH2CH2Br A? B? Pentane (g) Ether CH3CH2CH2CH2Br + (CH3)2CuLi ?II. Apply all the criteria for each reaction, and then draw the product(s) of each. a) b) 9 d) Br X² CH3CH₂O CH3 Br CH3 CH3 Br + j EtOH CH3CH₂CI CH3OH heat ? CH3ONa CH3OH ? ? i ? 1
- The following synthetic schemes all have at least one flaw in them. What is wrong with each? CH, „COOH 1. BH, 2. H,0 (a) ÇOOH 1. Mg 2 NaCN 3. H,0* (b) CH,CH,CHBrCH¿CH, CH,CH,CHCH,CH, „CH2COOH „CH,CH 1. LIAIH, 2. H,0* (e)7. Consider the following three step reaction. [4 (a) Add curved arrows in Step [1] to show the movement of electrons. H Lö: HÖ [1] + H-Ci: (b) Use the curved arrows drawn in Step [2] to identify the structure of X. X is converted in Step [3] to phenol and HCI. [2] + H-CI: [3] phenolQ4. The heating of the following compound will give which of the given products? A) H C) 中中 H B) H D) H H H