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- Ph HO Ph Ho Pn My 1Br THE 3) noreation PhNote these acronyms: HOAC = Acetic Acid; NaOAc = Sodium Acetate; THF = tetrahydrofuran Ph = Phenyl = C,Hs; DMSO = Dimethyl Sulfoxide, H;C-O-H = methanol, Zn = Zinc, D = heavy Hydrogen (1 proton and 1 neutron). Acetone = Acetic Acid = THF= Ph= .C. H3C CH3 H3C HO, 1. Write the products of the following reactions. If there is no reaction write NR. For full credit clearly indicate cis or trans relationships in cyclic compounds, where appropriate. h) 1) II,D-T IIr 21 HOOH. N2OH va ter sclvent i) 1) H,B THF 2) HOOH, NAOH water solvent j) CH 1)HB-THF 2) НООН, N:OH water solvent k) 1)O zUue 2) (CH ),SCH;COOOH 3. 3/9 Ph Ph Ph 4. ... ...
- Consider the following reaction: CH, ÇH, + :çi-A-Ci: H,C- A-: H,C- 50 CH3 Based on the reaction above, the reactant which acts as a Lewis base is CAICL CAICIs o(CH);CCI O(CH),C* The product which is a Lewis acid is OAICI O(CH,),cCI CAICI o(CH)C" The following salts can replace AICla in the reaction, except OBeCl OMgCl OFeCl ocrClsOH- + CH3COOH ==== CH3COO- + H2O. Which of the reactants is an acid?CH3 „Ph Ph. „CH3 H-SO4 > (А), HSO4 (B) 9. OH Product (A) & (B) respectively in the above reaction are : (а) Ph - С-NH -CHз, Ph - С-NH - СНз (Ъ) СНз - С-NH-Ph, СH3 - С-NH- Ph (c) Ph - С-NH - СН3, СНз — С-NH - Ph (d) CHз - С-NH-Ph, Ph - С-NH -СHз
- Part A: Please calculate pKa of formic acid below: (HCOOH H+ + HCOO-) Part B: What is pH of a solution containing 10 mM formic acid? G°f HCOOH = -372 kJ/molG°f HCOO- = -351 kJ/molG°f H+ = 0 kJ/mol11. Et O 1. CH3MGCI; 2.heat; H3C- 3. dil. HCI H3C = -CH2OH m. NC heat EN Ph OEt N2 n. Rh2(OAc)4 heat p.HO. COOH 7. (7a) + 2 NaOH _(7b) + NazCOa. +. H2O