b) Fill in the gaps by drawing the structures of the missing reagents, intermediates and/or products of the following electrophilic aromatic substitutions. Chemical formulas have been added for guidance. Step 1 Step 2 CH3 HNO3 H2 1. C6H5NO2 C,HgN H2SO4 `NO2 Pd/C 2 4 CH3 Br2/FeBr3 C3H;Bro 6 Using resonance structures, justify whether the acetyl group of compound 5 will direct the bromination reaction to the meta or ortho/para positions.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter21: Benzene And The Concept Of Aromaticity
Section: Chapter Questions
Problem 21.44P
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b) Fill in the gaps by drawing the structures of the missing reagents, intermediates and/or
products of the following electrophilic aromatic substitutions. Chemical formulas have been
added for guidance.
Step 1
Step 2
CH3
HNO3
H2
1.
C6H5NO2
C,HgN
H2SO4
`NO2
Pd/C
1
2
4
CH3
Br2/FeBr3
C3H;Bro
5
6
Using resonance structures, justify whether the acetyl group of compound 5 will direct the
bromination reaction to the meta or ortho/para positions.
Transcribed Image Text:b) Fill in the gaps by drawing the structures of the missing reagents, intermediates and/or products of the following electrophilic aromatic substitutions. Chemical formulas have been added for guidance. Step 1 Step 2 CH3 HNO3 H2 1. C6H5NO2 C,HgN H2SO4 `NO2 Pd/C 1 2 4 CH3 Br2/FeBr3 C3H;Bro 5 6 Using resonance structures, justify whether the acetyl group of compound 5 will direct the bromination reaction to the meta or ortho/para positions.
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