Aromatic Substitution Reactions1. Predict the major product(s) of the following reactions:CI(a)CH3CH2CIAICI 3(b)CH3CH2COCIAICI3CO₂H(c)HNO3H2SO4N(CH2CH3)2(d)SO3H2SO42. Which of the following reactions would give the product(s) indicated in substantial amounts (i.e., ingreater than 50% yield)?NH2AICI3NH2NH2CH36--6-8NH2+ CH3CIAICI3CH3NH2+ CH3CI+ CH3CH2CH2CIAICI 3CH3CH2CH2CH3

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Aromatic Substitution Reactions 1. Predict the major product(s) of the following reactions: CI CH3CH2CI (a) AIC 3 (b) CH3CH2COCI AICI3 CO₂H HNO3 (c) H2SO4

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

Aromatic Substitution Reactions
1. Predict the major product(s) of the following reactions:
CI
(a)
CH3CH2CI
AICI 3
(b)
CH3CH2COCI
AICI3
CO₂H
(c)
HNO3
H2SO4
N(CH2CH3)2
(d)
SO3
H2SO4
2. Which of the following reactions would give the product(s) indicated in substantial amounts (i.e., in
greater than 50% yield)?
NH2
AICI3
NH2
NH2
CH3
6--6-8
NH2
+ CH3CI
AICI3
CH3
NH2
+ CH3CI
+ CH3CH2CH2CI
AICI 3
CH3
CH2CH2CH3

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