Answer the following questions regarding the below structures : 1) which form is thermodinamically favored ? 2)For CO stretches in the cis and trans isomers ,do the stretches values give evidence of backbonding? 3)Could these isomers be distinguished by the number of IR active CO stretches (must have dipole change)? How many IR active?

Chemistry for Engineering Students
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ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.26PAE: The following data were collected for the reaction, H2(g) + L(g) ** - HI(g), at equilibrium at 25°C:...
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Answer the following questions regarding the below structures :

1) which form is thermodinamically favored ?

2)For CO stretches in the cis and trans isomers ,do the stretches values give evidence of backbonding?

3)Could these isomers be distinguished by the number of IR active CO stretches (must have dipole change)? How many IR active?

H
H
„CO
CO
Oc-Fe
ос—Fe—н
OC
CO
OC
H
ČO
trans-H2FE(CO)4
cis-H,Fe(CO)4
Transcribed Image Text:H H „CO CO Oc-Fe ос—Fe—н OC CO OC H ČO trans-H2FE(CO)4 cis-H,Fe(CO)4
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