Alkoxides R-O can be used to synthesize alkenes as exemplified by the reaction shov below, where the symbol (et) indicates that the substance is dissolved in ethanol (CH,CH,OH) used as solvent: Br (et) + (1) Br(et) + (et) CH,CH,OH t-but-Br Ethoxide Isobutylene 9. The table to the right shows the results for the initial rate of this reaction when performed under different conditions (four different trials) at 25 °C. What is the rate law for this reaction? Trial Initial Initial Initial Rate (M/s) a) Rate = k [t-but-Br] b) Rate = k [t-but-Br] [ethoxide] c) Rate = k [t-but-Br]? d) Rate = k [ethoxide]? [t-but-Br] [Ethoxide] [isobutylene] 6.8 x 10-8 13.6 x 10-8 6.8 x 10-8 13.6 x 10-8 1 0.08 M 0.04 M 2 0.16 M 0.04 M 3 0.08 M 0.08 M 4 0.16 M 0.08 M

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter10: Fuels, Organic Chemicals, And Polymers
Section: Chapter Questions
Problem 122QRT
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Alkoxides R-O- can be used to synthesize alkenes as exemplified by the reaction shov
below, where the symbol (et) indicates that the substance is dissolved in ethanol
(CH;CH,OH) used as solvent:
Br
(1) +
HO
Br(et)
(et) +
(et)
CH,CH,OH
t-but-Br
Ethoxide
Isobutylene
9. The table to the right shows the results for the initial rate of this reaction when
performed under different conditions (four different trials) at 25 °C. What is the rate
law for this reaction?
a) Rate = k [t-but-Br]
b) Rate = k [t-but-Br] [ethoxide]
c) Rate = k [t-but-Br]?
d) Rate = k [ethoxide]?
Trial
Initial
Initial
Initial Rate (M/s)
[t-but-Br]
[Ethoxide]
[isobutylene]
1
0.08 M
0.04 M
6.8 x 10-8
13.6 x 10-8
6.8 x 10-8
13.6 х 10-8
2
0.16 M
0.04 M
3
0.08 M
0.08 M
4
0.16 M
0.08 M
Transcribed Image Text:Alkoxides R-O- can be used to synthesize alkenes as exemplified by the reaction shov below, where the symbol (et) indicates that the substance is dissolved in ethanol (CH;CH,OH) used as solvent: Br (1) + HO Br(et) (et) + (et) CH,CH,OH t-but-Br Ethoxide Isobutylene 9. The table to the right shows the results for the initial rate of this reaction when performed under different conditions (four different trials) at 25 °C. What is the rate law for this reaction? a) Rate = k [t-but-Br] b) Rate = k [t-but-Br] [ethoxide] c) Rate = k [t-but-Br]? d) Rate = k [ethoxide]? Trial Initial Initial Initial Rate (M/s) [t-but-Br] [Ethoxide] [isobutylene] 1 0.08 M 0.04 M 6.8 x 10-8 13.6 x 10-8 6.8 x 10-8 13.6 х 10-8 2 0.16 M 0.04 M 3 0.08 M 0.08 M 4 0.16 M 0.08 M
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