a) The physical interpretation of the wavefunction and the fact that it is a solution of the Schroedinger equaton, which is a 2nd order differential equation, causes many restrictions on an acceptable wave function solution: (i) it must be single valued; (ii) it must be continuous; (iii) its slope must be continuous; and (iv) it must be normalizable or normalized. Sketch the following functions and check whether they can be wave function. Explain your answers. 1) Y(x) =, for 0 < x < ∞ 2) 4(x) = | sin(nx)|, for 0 < x < 2 3) Y(x) = In (x), for 1 < x < ∞ (0 for – 1 < x < 0 1+x - 4) ¥(x) = {1 for 0

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter12: Atoms And Molecules
Section: Chapter Questions
Problem 12.52E
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a) The physical interpretation of the wavefunction and the fact that it is a solution of the
Schroedinger equaton, which is a 2nd order differential equation, causes many
restrictions on an acceptable wave function solution: (i) it must be single valued; (ii) it
must be continuous; (iii) its slope must be continuous; and (iv) it must be normalizable
or normalized. Sketch the following functions and check whether they can be wave
function. Explain your answers.
1) 4(x) = for 0 < x <∞
2) Y(x) = | sin(nx)|, for 0 < x< 2
3) Ҹ(x) %3D In (x), for 1 < x < 0o
S0 for – 1 < x < 0
(1 for 0<x<1
1+x
4) Ҹ(x) 3D
Transcribed Image Text:a) The physical interpretation of the wavefunction and the fact that it is a solution of the Schroedinger equaton, which is a 2nd order differential equation, causes many restrictions on an acceptable wave function solution: (i) it must be single valued; (ii) it must be continuous; (iii) its slope must be continuous; and (iv) it must be normalizable or normalized. Sketch the following functions and check whether they can be wave function. Explain your answers. 1) 4(x) = for 0 < x <∞ 2) Y(x) = | sin(nx)|, for 0 < x< 2 3) Ҹ(x) %3D In (x), for 1 < x < 0o S0 for – 1 < x < 0 (1 for 0<x<1 1+x 4) Ҹ(x) 3D
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9781133958437
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Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,