A researcher was attempting to quantify the amount of dichlorodiphenyltrichloroethane (DDT) in spinach with gas chromatography using a chloroform internal standard. To begin, the researcher examined a sample containing 7.44 mg/L. DDT standard and 4.00 mg/L chloroform as the internal standard, producing peak areas of 3343 and 10837, respectively. Then, the researcher collected 11.93 g of spinach, homogenized the sample, and extracted the DDT using an established method (assume 100% extraction), producing a 2.00 ml volume of unknown sample. The researcher then prepared a sample that contained 0.500 ml of the unknown sample and 1.25 ml of 11.99 mg/L chloroform, which was diluted to a final volume of 25.00 ml. The sample was analyzed using GCMS, producing peak areas of 6371 and 12657 for the DDT in the unknown and the chloroform, respectively. Calculate the DDT concentration in the spinach sample. Express the final answer as milligrams of DDT per gram of spinach.
A researcher was attempting to quantify the amount of dichlorodiphenyltrichloroethane (DDT) in spinach with gas chromatography using a chloroform internal standard. To begin, the researcher examined a sample containing 7.44 mg/L. DDT standard and 4.00 mg/L chloroform as the internal standard, producing peak areas of 3343 and 10837, respectively. Then, the researcher collected 11.93 g of spinach, homogenized the sample, and extracted the DDT using an established method (assume 100% extraction), producing a 2.00 ml volume of unknown sample. The researcher then prepared a sample that contained 0.500 ml of the unknown sample and 1.25 ml of 11.99 mg/L chloroform, which was diluted to a final volume of 25.00 ml. The sample was analyzed using GCMS, producing peak areas of 6371 and 12657 for the DDT in the unknown and the chloroform, respectively. Calculate the DDT concentration in the spinach sample. Express the final answer as milligrams of DDT per gram of spinach.
Chapter8: Sampling, Standardization, And Calibration
Section: Chapter Questions
Problem 8.16QAP
Related questions
Question
Please don't provide handwritten solution ....
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 5 steps with 5 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
EBK A SMALL SCALE APPROACH TO ORGANIC L
Chemistry
ISBN:
9781305446021
Author:
Lampman
Publisher:
CENGAGE LEARNING - CONSIGNMENT
EBK A SMALL SCALE APPROACH TO ORGANIC L
Chemistry
ISBN:
9781305446021
Author:
Lampman
Publisher:
CENGAGE LEARNING - CONSIGNMENT
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning