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Organic Chemistry: A Guided Inquiry

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

ChapterNW4: Nomenclature Worksheet 4: Carbonyl Compounds

Section: Chapter Questions

Problem 1CTQ

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Question

A
OH
OH
HO
OH
OH
oints)
B
C
D
a. Which alcohol is the most soluble in water?
b. Which compounds contain a primary alcohol?
C.
Which is the most acidic alcohol?
Which alcohols will have a doublet in their HNMR?
d. Which alcohol(s) have a chiral center?
e.
f.
Which alcohol will have the most signals in their CNMR?
g. Which alcohol will have the highest boiling point?

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Label the stereogenic center(s) in each drug as R or S. L-Dopa is used to treat Parkinson's disease (Chapter 1). Ketamine is an anesthetic. Enalapril belongs to a class of drugs called ACE inhibitors, which are used to lower blood pressure. CH3 NHẠC CH,CH,Oz a. HO OH COOH HÌNH, L-dopa b. ketamine H enalapril Trade name: Vasotec CO₂H
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1. Label the following as a: diasteriomer, enantiomer or neither (different compound) CHO CHO a. H OH -HO- a. HO H and H OH HO- H OH CH,OH ČHHOH b. СНО СНО H OH HO H b. H OH HO H and H OH HO H H OH HO H ČH2OH 2. Indicate whether each of the following molecules are chiral or achiral. Circle the chiral carbon(s) if present in the structure. HOHO CH 3 H C=C%3DC%3DC BICH 2 C-CH 2CH 3 H3C CH3 H. b. а. C.
1. Draw all possible stereoisomers of the structures below. Indicate the isomeric relationships between all pairs of stereoisomers in each box. In each original structure, circle the stereocenters. D. E. NH2 OMe
5. Identify the type of each compound based on the function group it contains. (EOCQ 60) Compound Type of compound CH3-CH2-CH-CH2-CH3 Amine e.g NH2 нонн a. н-с-с-с-С-н H. нн CH3-CH2-CH2-NH2 CH3-0-CH3 С. HHHH O IIIII Н-С-С-С-С-С-ОН d. H HHH е. CH,-C-O-CH, f. CH3-CH2-CH2-NH2 g. H-C-C CH,CH, h. HICIH b.
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