- A method for the analysis of a metal ion (M2+) in water from the duck pond at Tech suffers from the erference from another metal (N+2). When the concentration of M²+ is 100 times greater than that of N²+, 105% What in the coloctivity coefficient for this method?

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
ChapterA1: Evaluation Of Analytical Data
Section: Chapter Questions
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.A). A method for the analysis of a metal ion (M2+) in water from the duck pond at Tech suffers from the
interference from another metal (N+2). When the concentration of M²+ is 100 times greater than that of N²+,
an analysis for M²+ has a relative error of +0.5%. What is the selectivity coefficient for this method?
B). A group of researchers describe a fluorescence method for the analysis of Ag* in water. When analyzing
a solution that contains 1.0 x10-9 M Ag* and 1.1 x10-7 M Ni²+, the fluorescence intensity was +4.9% greater
than that obtained for a sample of 1.0 x10-⁹ M Agt. Calculate the selectivity coefficient for Ag* with respect to
Ni+2 for this analytical method?
Transcribed Image Text:.A). A method for the analysis of a metal ion (M2+) in water from the duck pond at Tech suffers from the interference from another metal (N+2). When the concentration of M²+ is 100 times greater than that of N²+, an analysis for M²+ has a relative error of +0.5%. What is the selectivity coefficient for this method? B). A group of researchers describe a fluorescence method for the analysis of Ag* in water. When analyzing a solution that contains 1.0 x10-9 M Ag* and 1.1 x10-7 M Ni²+, the fluorescence intensity was +4.9% greater than that obtained for a sample of 1.0 x10-⁹ M Agt. Calculate the selectivity coefficient for Ag* with respect to Ni+2 for this analytical method?
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