A flavin-dependent enzyme catalyzes the transformation shown below. NH₂ FAD NH₂ a) Circle the specific class of enzymes below to which this flavin-dependent enzyme most likely belongs. oxidase monooxygenase (FMO) b) Circle the co-substrate this enzyme requires for activity. NAD(P)+ NAD(P)H c) Circle the co-product this enzyme produces. H₂O H₂O2 Baeyer-Villiger monooxygenase (BVMO) reductase no co-substrate required Neither d) Provide a complete curved-arrow mechanism for the transformation shown above. You should draw all reaction intermediates in their most stable resonance form wherever possible. Be sure your mechanism shows the formation of all co-products. You may continue your mechanism onto the next page if necessary.
A flavin-dependent enzyme catalyzes the transformation shown below. NH₂ FAD NH₂ a) Circle the specific class of enzymes below to which this flavin-dependent enzyme most likely belongs. oxidase monooxygenase (FMO) b) Circle the co-substrate this enzyme requires for activity. NAD(P)+ NAD(P)H c) Circle the co-product this enzyme produces. H₂O H₂O2 Baeyer-Villiger monooxygenase (BVMO) reductase no co-substrate required Neither d) Provide a complete curved-arrow mechanism for the transformation shown above. You should draw all reaction intermediates in their most stable resonance form wherever possible. Be sure your mechanism shows the formation of all co-products. You may continue your mechanism onto the next page if necessary.
Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Chapter20: Enzymes
Section: Chapter Questions
Problem 20.12E
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Transcribed Image Text:A flavin-dependent enzyme catalyzes the transformation shown below.
NH₂
FAD
NH₂
a) Circle the specific class of enzymes below to which this flavin-dependent enzyme most likely belongs.
oxidase
monooxygenase
(FMO)
b) Circle the co-substrate this enzyme requires for activity.
NAD(P)+
NAD(P)H
c) Circle the co-product this enzyme produces.
H₂O
H₂O2
Baeyer-Villiger
monooxygenase
(BVMO)
reductase
no co-substrate
required
Neither
d) Provide a complete curved-arrow mechanism for the transformation shown above. You should draw all
reaction intermediates in their most stable resonance form wherever possible. Be sure your mechanism
shows the formation of all co-products. You may continue your mechanism onto the next page if necessary.
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