A cell consisting of a saturated calomel electrode and a lead ion electrode developed a potential of -0.3257 V when immersed in a 60.00 mL lead solution of unknown concentration. A 10.00 mL addition of 0.02500 M lead standard solution caused the reduction potential to shift to -2897 V. Calculate the molar concentration (in units mM) of lead in the sample.

Fundamentals Of Analytical Chemistry
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Chapter21: Potentiometry
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Problem 21.26QAP
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Question 14
A cell consisting of a saturated calomel electrode and a lead ion electrode developed a potential of -0.3257 V when immersed in a 60.00 mL lead
solution of unknown concentration. A 10.00 mL addition of 0.02500 M lead standard solution caused the reduction potential to shift to -2897 V.
Calculate the molar concentration (in units mM) of lead in the sample.
Transcribed Image Text:Question 14 A cell consisting of a saturated calomel electrode and a lead ion electrode developed a potential of -0.3257 V when immersed in a 60.00 mL lead solution of unknown concentration. A 10.00 mL addition of 0.02500 M lead standard solution caused the reduction potential to shift to -2897 V. Calculate the molar concentration (in units mM) of lead in the sample.
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