a) Calculate the pH of an aqueous solution of the salt NaA, which was made to a concentration of 0.080 M NaA. The Ka of the weak acid HA is 2.0 x 10-5. Your pH should go to two places past the decimal point (i.e. 1.35). b) Aniline, C6H5NH2, has a pKb of 9.40. What is the pH of a solution which is 0.12 M in aniline and 0.38 M in anilinium ion, C6H5NH3+? Your answer should be to two places past the decimal.

a) Calculate the pH of an aqueous solution of the salt NaA, which was made to a concentration of 0.080 M NaA. The Ka of the weak acid HA is 2.0 x 10-5. Your pH should go to two places past the decimal point (i.e. 1.35). b) Aniline, C6H5NH2, has a pKb of 9.40. What is the pH of a solution which is 0.12 M in aniline and 0.38 M in anilinium ion, C6H5NH3+? Your answer should be to two places past the decimal.

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter21: The Chemistry Of The Main Group Elements

Section: Chapter Questions

Problem 78PS

See similar textbooks

Similar questions

The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10–8. (a)The undiluted bleach contains roughly 1 M NaClO. Calculate the pH of 1 M NaClO solution. (b)Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000 -fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation. (c)Suppose the solution in (a) is diluted by 1million-fold, briefly explain how your approach will be different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.
The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10–8. (a) The undiluted bleach contains roughly 1 M NaClO.Calculate the pH of 1 M NaClO solution. (b) Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000-fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation. (c) Suppose the solution in (a) is diluted by 1 million-fold, briefly explain how your approach willbe different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.
Determine the pH of each of the following solutions (Ka and Kb values can be found in the appendices of your textbook or online): (a) 0.045 M hypochlorous acid; (b) 0.0068 M phenol; (c) 0.080 M hydroxylamine.
The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10^–8. (a) The undiluted bleach contains roughly 1 M NaClO. Calculate the pH of 1 M NaClO solution. (b) Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000 -fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation. (c) Suppose the solution in (a) is diluted by 1 million-fold, briefly explain how your approach will be different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.
6. (i) Define pH in words. The strong acid HClag has a pH value of 1, use the following equation for a strong acid: HClaa Hog + and convert the following expression to deduce the hydrogen ion concentration: pH = -log10 [H+] Clea (ii) Use the above expression to deduce the pH of HCl (ag) given the concentration of the acid to be 4.5 mol/dm³ pH =
8. (a) HA(aq) is a weak acid with a dissociation constant, Ka, of 8.8 x 10−12. What is the pH of a 0.022 M solution of A−(aq)? The temperature is 25 ◦C. (b) For the reaction A(g) =A(l), the equilibrium constant is 0.666 at 25.0 ◦C and 0.222 at 75.0 ◦C. Making the approximation that the entropy and enthalpy changes of this reaction do not change with temperature, at what temperature will the equilibrium constant be equal to 0.777?
What concentration of oxalic acid, HOOCCOOH(H2A), will have a pH of 2.50 (pKa1 = 1.25; pKa2 = 4.14)?
The ionization constant of lactic acid, CH,CH(OH)CO,H, an acid found in the blood after strenuous exercise, is 1.36 x 10-4. What is the concentration of hydronium ion in the solution of 0.102 M lactic acid? CH;CH(OH)CO,H (aq) + H,O (1) → H;O• (aq) + CH;CH(OH)CO, (aq) O 0.00372 M O 0.0165 M O 0.00549 M O 0.227 M
COHSOH(ag) + H2On + CeHsO (aq) + H3O*(a9) Ka= 1.12 x 10-10 (a) Phenol is a weak acid that partially dissociates in water according to the equation above. Write the equilibrium-constant expression for the dissociation of the acid in water. (b) What is the pH of a 0.75 M CaHsOH(ag) solution? (C) For a certain reaction involving CaHsOH(ag) to proceed at a significant rate, the phenol must be primarily in its deprotonated form, C3H5O (eg). In order to ensure that the CsHsOH(aq) is deprotonated, the reaction must be conducted in a buffered solution. On the number scale below, circle each pH for which more than 50 percent of the phenol molecules are in the deprotonated form (CoHsO (aq). Justify your answer. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Justification: (d) CeHsOH(ag) reacts with NaOH(ag). Write a net ionic equation representing this reaction (aka: invasion equation). (e) What is the pH of the resulting solution when 30 mL of 0.40 M CSH5OH(aq) is added to 25 mL of 0.60 M NAOH. Show all work…
Q3. This question is about the pH of several solutions. Give all values of pH to 2 decimal places. (a) (i) Write an expression for pH. (b) (ii) Calculate the pH of the solution formed when 10.0 cm³ of 0.154 mol dm-³ hydrochloric acid are added to 990 cm³ of water. The acid dissociation constant, Ka, for the weak acid HX has the value 4.83 x 10-5 mol dm-³ at 25 °C. A solution of HX has a pH of 2.48 Calculate the concentration of HX in the solution. Page 4 of 14
If the Kb for hydrazine, N2H4(aq), is 1.7 x 10-6 , calculate the pH of a 1.8 mol/L solution of hydrazine.
The pH reading of a glass of liquid is given. Find the hydrogen ion concentration of the liquid. (Give your answers in scientific notation, correct to one decimal place.) (а) Вeer: pH = 5.3 [H+] = х 10 M (b) Water: pH = 7,2 [H+] = х 10 M