A buffer is prepared using lactic acid (HLac) and sodium lactate (NaLac). 0.300 dm3 of the 0.500 mol·dm–3 HLac solution is mixed with 0.300 dm3 of the 0.300 mol·dm–3 NaLac solution to prepare the buffer. Ka for lactic acid (HLac) is 1.4 x 10-4  What will the pH of the above solution be after 5.0 cm3 of 0.200 mol·dm–3 NaOH has been added to only 100.0 cm3 of this buffer?

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter4: Reactions In Aqueous Solution
Section: Chapter Questions
Problem 78QAP: When 85.0 mL of 0.250 M Ba(OH)2 solution is added to 85.00 mL of 0.250 M Al (NO3)3 solution, a white...
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1. A buffer is prepared using lactic acid (HLac) and sodium lactate (NaLac). 0.300 dm3 of the
0.500 mol·dm–3 HLac solution is mixed with 0.300 dm3 of the 0.300 mol·dm–3 NaLac solution
to prepare the buffer. Ka for lactic acid (HLac) is 1.4 x 10-4

 What will the pH of the above solution be after 5.0 cm3 of 0.200 mol·dm–3 NaOH has
been added to only 100.0 cm3 of this buffer?

2. Data in the table below were collected at 25°C for the following reaction:
2 I

(aq) + S2O8
2–
(aq) I2 (aq) + 2 SO4
2-
(aq)

a) Determine the rate law for the reaction. 
b) Calculate the rate constant, giving the correct units for k.

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