6. The crystal field splittings, A, are listed below for three ammine complexes of chromium. Explain the differences in values. Complex [CrF6]³- [Cr[OH₂)6]³+ [ [Cr (NH₂)6] ³ [Cr[CN)6]³- A(cm-¹) 15,000 17,400 22,000 26,600

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 71QRT
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6. The crystal field splittings, A, are listed below for three ammine complexes of chromium.
Explain the differences in values.
Complex
[CrF6]³-
[Cr[OH₂)6]³+
1 [Cr (NH3) 6]"
3-
[Cr[CN)6]³-
A(cm-¹)
15,000
17,400
22,000
26,600
Transcribed Image Text:6. The crystal field splittings, A, are listed below for three ammine complexes of chromium. Explain the differences in values. Complex [CrF6]³- [Cr[OH₂)6]³+ 1 [Cr (NH3) 6]" 3- [Cr[CN)6]³- A(cm-¹) 15,000 17,400 22,000 26,600
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