6. (a) Write down an expression for the volume difference dV between two equilibrium states in which the temperature and pressure differ by dT and dP respectively, T and P being independent. (b) Write down a similar expression for the pressure difference dP between two equilibrium states in which T and V are independent. (c) Proceed to show that the partial derivatives are related by: av ӘР == (-), (²), ()₁ = -1

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6. (a) Write down an expression for the volume difference dV between
two equilibrium states in which the temperature and pressure differ by
dT and dp respectively, T and P being independent.
(b) Write down a similar expression for the pressure difference dP
between two equilibrium states in which T and V are independent.
(c) Proceed to show that the partial derivatives are related by:
(₁),₂=
=-1
OP
ar/v
av/p
Transcribed Image Text:6. (a) Write down an expression for the volume difference dV between two equilibrium states in which the temperature and pressure differ by dT and dp respectively, T and P being independent. (b) Write down a similar expression for the pressure difference dP between two equilibrium states in which T and V are independent. (c) Proceed to show that the partial derivatives are related by: (₁),₂= =-1 OP ar/v av/p
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