6) 25pis Draw the structure of the major alkene product (or products) formed by treatment of each of the following haloalkanes with sodium ethoxide in ethanol. Assume the mechanism is E2 elimination. t-BuO K t-BUOH Br CH3 Eto Na F ELOH CH2CH3 CI- Eto Na -CH2CH3 ELOH H- ČH3 Br EtO Na ETOH CH3 CI H CH2CH3 Eto Na H3C ELOH H D

6) 25pis Draw the structure of the major alkene product (or products) formed by treatment of each of the following haloalkanes with sodium ethoxide in ethanol. Assume the mechanism is E2 elimination. t-BuO K t-BUOH Br CH3 Eto Na F ELOH CH2CH3 CI- Eto Na -CH2CH3 ELOH H- ČH3 Br EtO Na ETOH CH3 CI H CH2CH3 Eto Na H3C ELOH H D

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter10: Alcohols

Section: Chapter Questions

Problem 10.52P: Alcohols are important for organic synthesis, especially in situations involving alkenes. The...

See similar textbooks

Similar questions

What is the major product formed when 3-methyl-1-butene is treated with Hg(C2H3O2)2 in a THF/ethanol mixture followed by NaBH4 in base?
State what alkene or alkyne (with only carbons and hydrogens) and what other reactants you should use to most effectively synthesize the following in the fewest number of steps and with the highest yield. H;C-CH,- C CH3
Provide the structure(s) of the expected major organic product of the reaction shown. 1) Disiamylborane 2) H₂O₂, NaOH OI O II ||| O IV OV CH3CH₂C(CH3)2C=CH OH OH xx xo IV
One compound that contributes to the “seashore smell” at beaches in Hawai‘i is dictyopterene D', a component of a brown edible seaweed called limu lipoa. Hydrogenation of dictyopterene D' with excess H2 in the presence of a Pd catalyst forms butylcycloheptane. Ozonolysis with O3 followed by (CH3)2S forms CH2(CHO)2, HCOCH2CH(CHO)2, and CH3CH2CHO. What are possible structures of dictyopterene D'?
(CH3)2C=O A II. Draw the structure for the major organic product of each of the following reactions. 1) O3 7. 2) Me2s 3) H2, Pd/C low pressure 8. 1) PhMgBr 2) H2O, H3O* CN
Alcohols are important for organic synthesis, especially in situations involving alkenes. The alcohol might be the desired product, or the OH group might be transformed into another functional group via halogenation, oxidation, or perhaps conversion to a sulfonic ester derivative. Formation of an alcohol from an alkene is particularly powerful because conditions can be chosen to produce either the Markovnikov or non-Markovnikov product from an unsymmetrical alkene. Using your reaction roadmap as a guide, show how to convert 4-methyl-1-pentene into 5-methylhexanenitrile. You must use 4-methyl-1-pentene and sodium cyanide as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.
Which alkene when hydrochlorinated (hydrohalogenation reaction) will give this alkyl halide as product H3C CH3 CI CH3 2-methyl-1-pentene 2,3-dimethyl-1-pentene 2-methyl-2-butene 3-methyl-2-pentene
Which represents an efficient synthetic route to go from an alkane to an alkene? O elimination with NaNH2, followed by a water workup O anti-Markovnikov hydrohalogenation, followed by elimination O radical bromination, followed by elimination O hydration, followed by elimination O hydration, followed by ozonolysis of the double bond
An alkene G (C6H12) reacts with cold basic KMnO4 to produce H (C6H14O2). Hydrogenation of Gproduces I (C6H14). Ozonolysis of G produces propanone (CH3COCH3) and propanal(CH3CH2CHO).a) Draw the structure of G, H, I.b) State the reagent(s) and condition for ozonolysis reaction
2. Complete the following reactions of alkenes by drawing the structures of the major products. Include stereochemistry where relevant. 1) ВН, ТHF 2) Н,О2, ОН
Draw the structure for an alkene that gives the following reaction product. 1. Hg(OАc)2, Н2О ? -CHCH3 2. NABH4 ОН Ignore alkene stereochemistry. You do not have to explicitly draw H atoms. In cases where there is more than one answer, just draw one. Visited opy aste ChemDoodle
Draw the structure of the major product of benzene + CH3CH2CH2Cl in AlCl3