5. Write the equation for the iodination of the triacylglycerol: CH:-0-CO-(CH;);(CH = CHCH,); CH¸CH; ÇH-0-CO-(CH,),(CH = CHCH.);CH.CH; CH; -0-Co-(CH,); CH = CH (CH;);CH;
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- Q.2: Explain how to prepare polymeric gasoline from acetaldehyde. (a.) Give an acceptable name for compound C. (b) Draw the organicproducts formed when C is treated with each reagent: [1] H3O+; [2] −OH,H2O; [3] CH3CH2CH2MgBr (excess), then H2O; [4] LiAlH4, then H2O.What is an appropriate stepwise synthesis for 1-pentanol from butanal? NABH4/CH3OH; PBr3; Mg/ether; H;C , H3O* CH3 NABH4/CH3OH; PBr3; Mg/ether; ;H30* H' H. NaBH4/CH3OH; Mg/ether; ;H30* NABH4/CH3OH; Mg/ether; H3C , H3O* CH3 NABH4; PB13; Mg/ether; H' H.
- Reaction between CH;OCH3 and H2NCH; will give the following compound. (a) CH;OCH2CH,NH2 (b) CH;CN(CH3)CH; (c) CH;CH2CH2CH;N (d) CH;CN(CH3)CH,CH32. Compound A, C;H100 , is one of the basic building blocks of nature. All steroids and many other naturally occuring compounds are built from compound A. Spectroscopic analysis of A yields the following information: IR: 3400 cm-'; 1640 cım- IH NMR: 1.63 & (3 H, singlet); 1.70 ô (3 H, singlet); 3.83 6 (1 H, broad singlet); 4.15 8 (2 H, doublet, j = 7 Hz); 5.70 ô (1 H, triplet, ) = 7 Hz) (a) How many double bonds and/or rings does A have? (b) From the IR spectrum, what is the identity of the oxygen-containing functional group? (c) What kinds of protons are responsible for the NMR absorptions listed ? (d) Propose a structure for A.Question 5 of 50 -/1 > View Policies Current Attempt in Progress When (S)-2-bromopropanoic acid [(S)-CH3CHBPCO,H] reacts with concentrated sodium hydroxide, the product formed (after acidification) is (R)-2-hydroxypropanoic acid [(R)-CH3CHOHCO2H, commonly known as (R)-lactic acid). This is, of course, the normal stereochemical result for an SN2 reaction. However, when the same reaction is carried out with a low concentration of hydroxide ion in the presence of Ag,0 (where Ag* acts as a Lewis acid), it takes place with overall retention of configuration to produce (S)-2- hydroxypropanoic acid. The mechanism of this reaction involves a phenomenon called neighboring-group participation. Explain why there is a net retention of configuration when Ag* and a low concentration of hydroxide are used. The reaction is a two step process. The missing product produced by step 1 is: (Use single up and single down wedges to show the stereochemistry at the chiral center.) Step I Ag+ H Br CH,
- Choose the most appropriate reagent(s) to selectively reduce the ketone functional group to an alcohol in the following molecule: (a) NaBH4, then aqueous acid (b) LIAIH, then aqueous acid (c) H2NNH, then KOH, heat (d) H, Pd/C (e) none of (a), (b), (c) or (d) can be used a. b.For each pair of ions, determine which ion is more stable. Use resonance forms to explain your answers. (a) CH;-CH-CH, or CH,-CH-OCH, (b) CH;-N-CH, CH3-CH-CH; or CH;-C-CH; CH;-C-CH, (c) CH=CH-ČH-CH, or CH,=CH-CH;-CH2 (d) CH-CH, or CH,-C N: (e) CH2 CH2 () or or3. Plants of the Euphorbia genus exude a "milky irritant latex" and have a wide range of medically relevant activities (antiviral, anti-proliferative, anti-inflammatory, anti- drug resistance). The natural product (+)-pepluanol A, a secondary metabolite of Euphorbia, has recently been synthesized. (Yuan, P.; Gaich, T.; Org. Lett., 2022, in press.) a) How many chiral centers does (+)-pepluanol A have? b) In which direction does pure (+)-pepluanol A rotate the plane of polarized light? Me,, Me Me Me $ "H H OH Me Me (+)-pepluanol A
- (THF); (Chloromethyl)oxirane (epichlorohydrin); furoic acid is.. Which of the following heterocyclic compounds (furfural, tetrahydrofuran ************* 1- Used as a good common solvent: 2- Is prepared industrially from plant residues 3- Used as a starting materials for synthesis of epoxy resin 4- Is used for synthesis of medications and perfumes CHO furfural tetrahydrofuran 2-(chloromethyl)oxirane furoic acidSelect the appropriate synthetic route to convert methylcyclobutane into cyclopentene. ?? 1 1. KOtBu; 2. BH3-THF; 3. H₂O2, NaOH; 4: H₂SO4, heat 1. H₂, Lindlar's catalyst; 2. BH3-THF; 3. H₂O2, NaOH 1. Br₂, hv; 2. KOtBu; 3. BH3-THF; 4. H₂O2, NaOH; 5: H₂SO4, heat 1.BH3-THF; 2. H₂O2, NaOH; 3. H₂, Pt 1. Br₂, hv; 2. KOtBu; 3. H₂O₂, NaOH; 4: H₂SO4, heatDraw structures and provide IUPAC names for each of the following. (a) n-butyl chloride; (b) s-butyl iodide; (c) t-butylfluoride; (d) neopentyl bromide; (e) diisopropyl ether