5. Which one of the following structures represents the resonance contributor of a molecule in the box in agreement with the shown curved arrows? A) H,N=N=N: B) H,N-N=N: H,N NEN: C) H,N=N=N: D) H,N=N=N: OA
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- Which structures below are plausible resonance contributors for NCNH? Assume the connectivity is as written. II :N=C-N: H :N=C-NH II IV O N=C=NH O.. :N-CENH A) I and II B) I and III C) I and IV D) Il and III 0:ż:For each example, specify whether the two structures are resonance contributors to the same resonance hybrid. :0: а) H3C- H3C- :0: + b) H3C-NH-CH2 H3C-NH=CH2 CH2 CH2 c) CH2e) Describing the boding in ethene using VBT: One C=C bond, consisting of (state how many, 1,2,3 etc) (o or n) C-C bond/s formed from overlap of a orbital with a orbital and (state how many, 1,2,3 etc) (o or n) C-C bond/s formed from overlap of a orbital with a orbital. C-H bonds, (o or n) bonds formed from overlap of with
- Which of the following pairs are resonance structures? a) and b) :N-NEN: and :N= N= N: 2- c) HO and and H. e) CHz CHz CH= CHz CHz CH=CH CHz and CH3 CHz CHz CH CHz CHz CH3 f) CH, CH CHz CHzCHz and :ö: g) and CHz C=CH2Which of the following resonance structures has the greatest contribution to the hybrid? Explain. H. N E FWhich of these is not a valid resonance structure of A? :0: :0:0 ;0: A B D E D B) they are all valid E O © O O O
- Resonance, hybridization, Lewis structures: Draw the most important resonance contributor of the 1-methylcyclohexene ion Draw the most important resonance contributor of the following structure. Interactive 3D display mode CH₂ Draw the structure on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. NN [1] 7 L H: 2D EXP. CONT L Marvin JS by ChemAxon Z O I O S CI Br I P F1. Identify which resonance structures below are insignificant O-H :ở, :ö-H :ö-H H-0.Determine the relationship between Structure A and Structure B in each row of the table. H -O: H H Structure A :0: H H :O: H H H H H :S-C=N: H H H H Structure B :0: :0: H H H H H J ·0 :N=C—S H H H H H H isomers resonance structures neither isomers resonance structures neither Relationship isomers resonance structures neither ? olo Ar
- For each example, specify whether the two structures are resonance contributors to the same resonance hybrid. а) H2C-NH2 H2C=NH2 H,C=CH-Öit-CH, b) H2C-CH=CH-CH3 :ö: c) + H2C=CH-C–H H2C-CH=Ć-H :ö:Draw as many resonance structures as you can for the following spe- cies, adding appropriate formal charges to each: 2nd bios pigleM 2-S oslom boot dat vo slovo bios sitio edt bovlovni sonstedua s (a) Nitromethane, :O: +// H3C-N :0: Caislax Jon e..obbo.ilodstem o (b) Ozone, :0=0-0: HO- -OH Phenol 22=9.91 CH COH HO-O + .. (c) Diazomethane, H₂C=N=N: in Problem 2-44 is a strong enough acidDetermine whether the following pairs of structures are actually different compounds or simply resonance forms of the same compounds. 1-41 0 0 and and (b) (a) O +0-H O 0-H and and (d) +NH₂ 0 NH₂ CH,-!-H + (e) CH₂=C H and CH₂-CH (Đ) CH–C−NH, and CH3–C=NH, + (g) CH₂=CH-CH₂ and CH₂-CH=CH₂ (h) CH₂=C=0 and H=C=C—OH Ο Η 0 H 0 H +O-H (i)/H-C-C-H and H-C=C-H (j) H-C-H and H¬C-H g H H O- 유 0 « -l- + (k) H-C-NH₂ and H-C=NH₂ (1) CH₂-C-CH=CH₂ and CH₂-C=CH-CH₂