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- Mechanism: A reaction mechanism for the following reaction is shown below. H+ CEN CEN: N-H || -C-OH H₂O, H* Step 1 wand woled mot ozsm E Step 3 N-H C-OH C=N-H Step2 C=N-H H-O-H H₂O motno vgiene fesrigid onlt to smotnos -C=N-H a) The overall reaction is an example of b) Step 1 is c) Step 3 is d) Draw in the curved arrows for each step. e) Identify the nucleophiles and electrophiles where appropriate. f) Fill in the reaction energy diagram. H₂O: rate determining step to noipojovo hamwell sit 5(emise erit voittons 10) vanas mi sdgin al rainW di of E^ reaction progress →CH3 CH3 CH3 CH;=ĊCH,CHCH;OH H2SO4, H3C H3C Referring to the above reaction: 1. Which atom does the H2SO4 first remove? 2. Identify the reaction if it's hydrogenation, hydrohalogenation, etc. 3. Propose a mechanism for the reaction, using the arrow formalism to indicate the flow of electrons.Melamine, used as a fire retardant and a component of the writing surface of white boards, can be prepared from s-trichlorotriazine through a series of SNAr reactions with ammonia. The first substitution takes place rapidly at room temperature. The second substitution takes place near 100 °C, and the third substitution requires even higher temperature and pressure. Provide an explanation fatr this reactivity.
- The following carbocation is an intermediate in the electrophilic addition reaction of HCl with two different alkenes. Identify both, and tell which C-H bonds in the carbocation are aligned for hyperconjugation with the vacant p orbital on the positively charged carbon.As a rule, axial alcohols oxidize somewhat faster than equatorial alcohols. Which would you expect to oxidize faster, cis-4-tert-butylcyclo-hexanol or trans-4-tert-butylcyclohexanol? Draw the more stable chair conformation of each molecule.Addition of HCl to 1-isopropylcyclohexene yields a rearranged product. Propose a mechanism, showing the structures of the intermediates and using curved arrows to indicate electron flow in each step.
- 9. Draw the constitutional isomer formed when the following alkenes are treated with each set of reagents: [1] H20, H2SO4; or [2] BH3 followed by H2O2, "OH. A io onutouTC.rvinmmoo ewo ebyoleen.g er besibhoyn motis M doso al waH s b. a. Seblaar molsHsno isq onol nose 2eob isticho to eqyt ewni.d Cnistnoo ennug 29ob anodogle yoam woH.o O bns 18 to alnemala erlT nertw bemot witam-S ae doue anexie leohtemmyeniB. What type of elimination reaction is this: E1 or E2? Explain. C. Explain how the leveling effect has occurred in this reaction? D. What is the likely base in the last step: water or HSO4? Explain.For each reaction, decide whether substitution or elimination (or both) is possible, andpredict the products you expect. Label the major products. chlorocyclohexane + NaOCH3 in CH3OH