5. (a) Use the hydrogen-like model z2 (in eV) En =-13.6 to calculate the total energy of the three electrons of lithium (Li), which has the electron configuration: 1s 2s'. The three ionization energies for Li(g) are: IE, = 5.392 ev; IE2 = 75.64 eV; IE, = 122.5 eV. With the help of Koopman's theorem, what is the total energy of ropulsion between lithium's three electrons (in kJ mol')?

Principles of Modern Chemistry
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Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
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Chapter5: Quantum Mechanics And Atomic Structure
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Problem 55AP: The outermost electron in an alkali-metal atom is sometimes described as resembling an electron in...
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5. (a) Use the hydrogen-like model
z2
(in eV)
En --13.6
to calculate the total energy of the three electrons of lithium (Li), which
has the electron configuration: 1s? 2s'. The three ionization energies for
Li(g) are: IE, = 5.392 ev; IE2 = 75.64 eV; IE = 122.5 ev.
With the help of Koopman's theorem, what is the total energy of
ropulsion between lithium's three electrons (in kJ mol')?
Transcribed Image Text:5. (a) Use the hydrogen-like model z2 (in eV) En --13.6 to calculate the total energy of the three electrons of lithium (Li), which has the electron configuration: 1s? 2s'. The three ionization energies for Li(g) are: IE, = 5.392 ev; IE2 = 75.64 eV; IE = 122.5 ev. With the help of Koopman's theorem, what is the total energy of ropulsion between lithium's three electrons (in kJ mol')?
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