5) The volume of several aqueous copper sulfate (CuSO4) solutions was precisely measured at SATP. All of the solutions were made by adding copper sulfate to 100.00 g of water. ncopper sulfate (mol) Vsolution (mL) 0 100.18 0.0330 100.16 0.0696 100.36 0.111 100.81 0.156 101.62 First, estimate the concentration-dependent partial molar volume of copper sulfate in water by taking finite differences. Second, fit the data to a hyperbola and take a derivative of the hyperbola to accurately calculate the partial molar volume of copper sulfate in water at each concentration. Interpret the partial molar volume at infinite dilution - what must copper sulfate be doing to the nearby water molecules?
5) The volume of several aqueous copper sulfate (CuSO4) solutions was precisely measured at SATP. All of the solutions were made by adding copper sulfate to 100.00 g of water. ncopper sulfate (mol) Vsolution (mL) 0 100.18 0.0330 100.16 0.0696 100.36 0.111 100.81 0.156 101.62 First, estimate the concentration-dependent partial molar volume of copper sulfate in water by taking finite differences. Second, fit the data to a hyperbola and take a derivative of the hyperbola to accurately calculate the partial molar volume of copper sulfate in water at each concentration. Interpret the partial molar volume at infinite dilution - what must copper sulfate be doing to the nearby water molecules?
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter12: Solutions
Section: Chapter Questions
Problem 12.106QE: In the 1986 Lake Nyos disaster (see the chapter introduction), an estimated 90 billion kilograms of...
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