49. The kinetics of the reaction A + 3B → C + 2D were studied and the following results were obtained, A[A] where the rate law is At k[A]*[B]M. %3D For a run where [A]o = 1.0 x 10-3 M and [B]o = 5.0 M, a plot of ln[A] versus t was found to give a straight line with a slope equal to -5.0 x 10-2 s-l. %3D For a run where [A]o = 1.0 x 10-3 M and [B]o = 10.0 M, a plot of In[A] versus t was found to give a straight line with a slope equal to -7.1 x 10-2 s-l. What is the value of the rate constant, k, for this reaction? А. 1.1 x 10-1 В. 1.0 х 10-2 С. 2.2 х 10-2 D. 5.0 x 10-2 E. None of the above

Chemistry & Chemical Reactivity
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ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 6PS: 6. Phenyl acetate, an ester, reacts with water according to the equation The data in the table were...
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49. The kinetics of the reaction A + 3B → C + 2D were studied and the following results were obtained,
where the rate law is
At
A[A]
= k[A]"[B]m.
For a run where [A]o = 1.0 x 10-3 M and [B]o = 5.0 M, a plot of In[A] versus t was found to give a straight
line with a slope equal to -5.0 x 10-2 s-l.
For a run where [A]o= 1.0 x 10-3 M and [B]o = 10.0 M, a plot of In[A] versus t was found to give a
straight line with a slope equal to -7.1 x 10-2 s-l.
What is the value of the rate constant, k, for this reaction?
A. 1.1 x 10-1
В. 1.0 х 10-2
С. 2.2 х 10-2
D. 5.0 x 10-2
E. None of the above
Transcribed Image Text:49. The kinetics of the reaction A + 3B → C + 2D were studied and the following results were obtained, where the rate law is At A[A] = k[A]"[B]m. For a run where [A]o = 1.0 x 10-3 M and [B]o = 5.0 M, a plot of In[A] versus t was found to give a straight line with a slope equal to -5.0 x 10-2 s-l. For a run where [A]o= 1.0 x 10-3 M and [B]o = 10.0 M, a plot of In[A] versus t was found to give a straight line with a slope equal to -7.1 x 10-2 s-l. What is the value of the rate constant, k, for this reaction? A. 1.1 x 10-1 В. 1.0 х 10-2 С. 2.2 х 10-2 D. 5.0 x 10-2 E. None of the above
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