4. The structure provide is of (+)-4-bromo-2-methylpent-2-ene, what is the absolute configuration of the asymmetric center in (-)-4-bromo-2-methylpent-2-ene? Draw the structure of (-)-4-bromo- 2-methylpent-2-ene and assign the absolute configuration of its asymmetric center. Br

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4. The structure provide is of (+)-4-bromo-2-methylpent-2-ene, what is the absolute configuration
of the asymmetric center in (-)-4-bromo-2-methylpent-2-ene? Draw the structure of (-)-4-bromo-
2-methylpent-2-ene and assign the absolute configuration of its asymmetric center.
Br
5. For structures A-C, determine the type of radical.
A
D
B
b. (2R)-chloro-(5R)-methyloctane
E
6. Convert the following IUPAC name into a Lewis structure with dashed/wedge bonds to
properly show the stereochemistry at the two chiral/asymmetric centers.
a. (3S)-bromo-(5S)-methylheptane
C
major
F
7. Give a curved arrow-pushing mechanism for the following reaction and make sure to
include all nonbonding electrons. CLEARLY Indicate the initiation, propagation and
two termination steps, one which should account for formation of the minor product.
Br₂
Br
+
minor
Transcribed Image Text:4. The structure provide is of (+)-4-bromo-2-methylpent-2-ene, what is the absolute configuration of the asymmetric center in (-)-4-bromo-2-methylpent-2-ene? Draw the structure of (-)-4-bromo- 2-methylpent-2-ene and assign the absolute configuration of its asymmetric center. Br 5. For structures A-C, determine the type of radical. A D B b. (2R)-chloro-(5R)-methyloctane E 6. Convert the following IUPAC name into a Lewis structure with dashed/wedge bonds to properly show the stereochemistry at the two chiral/asymmetric centers. a. (3S)-bromo-(5S)-methylheptane C major F 7. Give a curved arrow-pushing mechanism for the following reaction and make sure to include all nonbonding electrons. CLEARLY Indicate the initiation, propagation and two termination steps, one which should account for formation of the minor product. Br₂ Br + minor
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