4. The reaction: 2 ClO2(aq) + 2 OH'(aq) → ClO;'(aq) + CIO2'(aq) + H2O(1) was studied with the following initial concentrations of reactants at 50°C: Experiment [cl0,] (M) [OH] (M) Initial Rate: (M/s) 1 0.060 0.030 0.0248 0.020 0.030 0.00276 3 0.020 0.090 0.00828 a) Determine the rate law for the reaction. b) Calculate the rate constant, k, for this reaction using the data from each run and then calculate the average value for the rate constant, k. c) Using the average value for the rate constant, calculate the initial rate of the reaction when the initial concentrations of the reactants are [CIO2] = 0.10M and [OH]= 0.050M.
4. The reaction: 2 ClO2(aq) + 2 OH'(aq) → ClO;'(aq) + CIO2'(aq) + H2O(1) was studied with the following initial concentrations of reactants at 50°C: Experiment [cl0,] (M) [OH] (M) Initial Rate: (M/s) 1 0.060 0.030 0.0248 0.020 0.030 0.00276 3 0.020 0.090 0.00828 a) Determine the rate law for the reaction. b) Calculate the rate constant, k, for this reaction using the data from each run and then calculate the average value for the rate constant, k. c) Using the average value for the rate constant, calculate the initial rate of the reaction when the initial concentrations of the reactants are [CIO2] = 0.10M and [OH]= 0.050M.
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 87QAP: A drug decomposes in the blood by a first-order process. A pill containing 0.500 g of the active...
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