4. Fill in the blanks. Acid Ка pKa Methanoic acid, HCOOH Ethanoic acid, CH3COOH Hydrocyanic acid, HCN Nitrous acid, HNO2 1.70 x 104 1.80 x 105 4.90 x 10-10 4.50 x 104 Carbonic acid, H2CO3 4.47 x 10-7 Hydrofluoric acid, HF 7.10 x 104 Base Kb pKb Ammonia, NH3 1.80 x 105 Hydrazine, N2H4 Ethylamine, C2H$NH2 Phenylamine, CeHsNH2 Urea, (NH2)2CO 1.80 x 105 5.60 x 104 3.80 x 10-10 1.5 x 10-14

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Chapter1: Chemical Foundations
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4. Fill in the blanks.
Acid
Ка
pKa
Methanoic acid, HCOOH
1.70 x 104
Ethanoic acid, CH3COOH
1.80 x 105
4.90 x 10-10
Hydrocyanic acid, HCN
Nitrous acid, HNO2
Carbonic acid, H2CO3
Hydrofluoric acid, HF
4.50 x 104
4.47 x 10-7
7.10 x 104
Base
Kb
pKb
Ammonia, NH3
1.80 x 10-5
Hydrazine, N2H4
Ethylamine, C2HŞNH2
Phenylamine, CgH$NH2
Urea, (NH2)2CO
1.80 x 10-5
5.60 x 104
3.80 x 10-10
1.5 x 10-14
5. The pH of a 0.15 M butylamine (C4H,NH2) solution is 12.0 at 298 K. Calculate
a) the dissociation constant of the base and
b) the degree of dissociation
6. Calculate the concentration of H• ions in a 0.2 M HCN solution. Given value of pKa for HCN is 9.3.
7. The pkb value of an aqueous solution of ammonia is 4.70. Calculate the concentration of OH- ions in 0.2 mol
dm3 ammonia solution.
8. The degree of dissociation of a monoprotic organic acid is 0.18% if its concentration is 0.01 M. Calculate
a) the dissociation constant
b) the pka value of this acid
C. Salt Hydrolysis
1. Determine each of the following acid-base reactions produce acidic, basic or neutral salt. Write the hydrolysis
reaction where applicable.
a) HNO3 + CH;NHz
b) HF + KOH
2
Transcribed Image Text:4. Fill in the blanks. Acid Ка pKa Methanoic acid, HCOOH 1.70 x 104 Ethanoic acid, CH3COOH 1.80 x 105 4.90 x 10-10 Hydrocyanic acid, HCN Nitrous acid, HNO2 Carbonic acid, H2CO3 Hydrofluoric acid, HF 4.50 x 104 4.47 x 10-7 7.10 x 104 Base Kb pKb Ammonia, NH3 1.80 x 10-5 Hydrazine, N2H4 Ethylamine, C2HŞNH2 Phenylamine, CgH$NH2 Urea, (NH2)2CO 1.80 x 10-5 5.60 x 104 3.80 x 10-10 1.5 x 10-14 5. The pH of a 0.15 M butylamine (C4H,NH2) solution is 12.0 at 298 K. Calculate a) the dissociation constant of the base and b) the degree of dissociation 6. Calculate the concentration of H• ions in a 0.2 M HCN solution. Given value of pKa for HCN is 9.3. 7. The pkb value of an aqueous solution of ammonia is 4.70. Calculate the concentration of OH- ions in 0.2 mol dm3 ammonia solution. 8. The degree of dissociation of a monoprotic organic acid is 0.18% if its concentration is 0.01 M. Calculate a) the dissociation constant b) the pka value of this acid C. Salt Hydrolysis 1. Determine each of the following acid-base reactions produce acidic, basic or neutral salt. Write the hydrolysis reaction where applicable. a) HNO3 + CH;NHz b) HF + KOH 2
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