31. (a) Calculate the pH of a mixture containing 0.1 M propanoic acid (CH3CH₂COOH) and0.050 M sodium propanoate (CH3CH₂COONa)(b) Determine the change in pH that occurs when 0.15 mol solid NaOH is added to 1.00litre of the buffered solution.32. (a) Calculate the pH of a buffer solution produced by adding 3.28 g of sodium ethanoateto 1 dm3 of 0.01 M of ethanoic acid (Ka = 1.84x 10-5 at 300K)(b) calculate the pH of this buffer if 10 cm3 of 0.1 M HCl are now added

Note: Since you have asked multiple questions in a single image. So according to guidelines here is…

31. (a) Calculate the pH of a mixture containing 0.1 M propanoic acid (CH3CH₂COOH) and 0.050 M sodium propanoate (CH3CH₂COONa) (b) Determine the change in pH that occurs when 0.15 mol solid NaOH is added to 1.00 litre of the buffered solution.

31. (a) Calculate the pH of a mixture containing 0.1 M propanoic acid (CH3CH₂COOH) and 0.050 M sodium propanoate (CH3CH₂COONa) (b) Determine the change in pH that occurs when 0.15 mol solid NaOH is added to 1.00 litre of the buffered solution.

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter15: Complex Ion And Precipitation Equilibria

Section: Chapter Questions

Problem 11QAP: A buffer is prepared by dissolving 0.0250 mol of sodium nitrite, NaNO2, in 250.0 mL of 0.0410 M...

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Acid Base Titration

An acid-base titration is the method of quantitative analysis for determining the concentration of an acid and base by exactly neutralizing it with a standard solution of base or acid having known concentration.

Question

31. (a) Calculate the pH of a mixture containing 0.1 M propanoic acid (CH3CH₂COOH) and
0.050 M sodium propanoate (CH3CH₂COONa)
(b) Determine the change in pH that occurs when 0.15 mol solid NaOH is added to 1.00
litre of the buffered solution.
32. (a) Calculate the pH of a buffer solution produced by adding 3.28 g of sodium ethanoate
to 1 dm3 of 0.01 M of ethanoic acid (Ka = 1.84x 10-5 at 300K)
(b) calculate the pH of this buffer if 10 cm3 of 0.1 M HCl are now added

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A buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to enough water to make 155 mL of solution. (a) What is the pH of the buffer? (b) If enough water is added to double the volume, what is the pH of the solution?
Acrylic acid is used in the polymer industry in the production of acrylates. Its K, is 5.6 X 10“’. What is the pH of a 0.11 M solution of acrylic acid, CH2CHCOOH?
A buffer is prepared by dissolving 0.0250 mol of sodium nitrite, NaNO2, in 250.0 mL of 0.0410 M nitrous acid, HNO2. Assume no volume change after HNO2 is dissolved. Calculate the pH of this buffer.
A buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to enough water to make 155 mL of solution. (a) What is the pH of the buffer? (b) If enough water is added to double the volume, what is the pH of the solution?
A buffer is prepared by adding 5.0 g of ammonia, NH3, and 20.0 g of ammonium chloride, NH4Cl, to enough water to form 2.50 L of solution. (a) What is the pH of the buffer? (b) Write the complete ionic equation for the reaction that occurs when a few drops of nitric acid are added to the buffer. (c) Write the complete ionic equation for the reaction that occurs when a few drops of potassium hydroxide solution are added to the buffer.
A buffer solution is prepared by dissolving 4.7 g of nitrous acid, HNO2 , and 13.8 g of sodium nitrite, NaNO2, in 1.0 liter of solution. (a) Calculate the pH of the buffer. (b) Calculate the pH of the solution which results when the following are added to separate 100 mL portions of the buffer: (i) 5.0 mmol of HCI; (ii) 5.0 mmol of NaOH. Ka = 4.5 x 104 %3D
A buffer is prepared by adding 20.0 g of sodium acetate(CH3COONa) to 500 mL of a 0.150 M acetic acid(CH3COOH) solution. (a) Determine the pH of the buffer.(b) Write the complete ionic equation for the reaction thatoccurs when a few drops of hydrochloric acid are added tothe buffer. (c) Write the complete ionic equation for the reactionthat occurs when a few drops of sodium hydroxidesolution are added to the buffer.
You are asked to prepare a pH = 3.00 buffer solution startingfrom 1.25 L of a 1.00 M solution of hydrofluoric acid(HF) and any amount you need of sodium fluoride (NaF).(a) What is the pH of the hydrofluoric acid solution priorto adding sodium fluoride? (b) How many grams of sodiumfluoride should be added to prepare the buffer solution?Neglect the small volume change that occurs when the sodiumfluoride is added.
A buffer solution was prepared that contained 0.60 M hydrogen fluoride, HF (Ka = 7.2 x 104) and 1.00M potassium fluoride, KF. The total volume was 250 mL. (a) What ions and molecules are present in the solution? List them in order of decreasing concentration: Decreasing order of Concentration (b) What is the pH of the buffer solution described above? (c) What is the pH of 100. mL of the buffer solution if you add 100. x 10-3 g of NaOH? Assume negligible change in volume. (USEFUL INFORMATION: MM NaOH = 39.997 g mol-1)
3) 2.0 g of NaOH is dissolved in distilled water to prepare 100 mL solution. 20.0 mL of this solution reaches to the equivalence point when 25 mL of an acid solution containing 1.22 g unknown monoprotic weak acid is added. (a) Calculate the molar mass of the unknown acid. (b) After 15.0 mL of NaOH solution had been added during the titration, the pH was determined to be 4.7. What is the Ka of the unknown acid? (NaOH = 40.0 g/mol)
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a) What is the pH of a buffer solution that is made by dissolving 125.5 g of sodium benzoate and 166.9g of benzoic acid in 500 mL of water? (b) What is the pH if you added 26.7 mL of 2.22 M NaOH to 254 mL of the buffer solution from above? (c) What is the pH if you added 32.8 mL of 3.36 M HCl to 354 mL of the buffer solution from above? Dont

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