bha 3./4/5./6. () Predict the major organic product(s). No mechanisms needed.CNHO, CNtCN1. LIAIH2. H*/H₂O1.2. H/H₂OMgCl1. NaOH, H₂O2. HH₂O*H₂O2

Given are organic reactions.Let's see products for each reaction,

Answered: 3./4/5./6. () Predict the major organic…

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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1. What is the major organic product generated in the reaction sequence below? (A) ...OH CH3 (B) CH3 OH |||||CH3 "||||||OH 1. H₂SO4/ heat 2. Hg(OAc)2 / H₂O 3. NaBH4 (C) |||||CH3 OH (D) OH CH3
With which of the following reaction conditions I, II and III, the reaction below will afford a diol as the major organic product? (1) 1. Excess CH3MgBr; 2. H3O+. (II) 1. Excess LiAlH4; 2. H3O+. (III) Excess NaBH4, CH3OH. O I only O II only O III only I and II only O I and III only II and III only O I, II and III
In each reaction box, place the best reagent and conditions from the list provided. 1) Br 2) 3) DEET 4) (the active ingredient in over the counter insect repellant) 5) Answer Bank SOCI, НСООCH, Br,, FeBr, H,0+ HN(CH,CH,), (1 equiv.) H,CO NH(CH,CH,),(2 equiv.) Mg. Et,0 NaCN CH,CH,NH, CH;CH, Br CO, NANH, НСООН CH,COOH CH,CH,OH
In each reaction box, place the best reagent and conditions from the list provided. 1) Br 2) 3) 4) DEET (the active ingredient in over the counter insect repellant) 5) Answer Bank Mg, Et,0 HN(CH, CH, ), (1 equiv.) H,O* CH,COOH CH,CH,NH, CH,CH, Br NH(CH,CH,),(2 cquiv.) НСООСH, H,CO НСООН CH, CH, OH NaCN NaNH, Br,, FeBr, SOCI, CO,
© (7) (8) (9) CHO CHO Br₂ ACOH + HCHO ( con. NaOH OH™ .CI AICI 3 ) ( ) )+ HCOO CH₂MgBr ( (a-halogenation) (Crossed cannizzaro reaction) (Crossed aldol reaction) )
3. Draw the reaction mechanism for the following reactions. When possible, label nucleophiles/electrophiles, carbocations, and oxonium ions. H* CI. a) H. + H2O + НОCHЗ H* OH H* H;C
Arrange the ff. in their decreasing order (easiest first) of relative ease in the acid-catalyzed esterification of ethyl alcohol: I. (CH);CHCOOH II. CH;CH,COOH HI. (CH-);COOH A) III, II, I I, II, II II, I, II II, III, I
What is the expected major product for the following reaction? O IV I OCH 3 |||||... + enantiomer || 1. Hg(OAc)2, CH3OH 2. NaBH4 НО. OH ... H3CO. + enantiomer ||| IV H3CO V
*(f) 1. xs 1. i-PrMgBr - abbreviation 6 2. H20 2. H20 Isopropyl 4-oxo- pentanoate Excess isoprору! magnesium bromide followed by water
3. Write the product (s) formed in the following reactions. OH conc. HCI 1) DMSO/ (COCI), 2 eq/-60 °C 2) Et,N (excess) НО PCC/CH,Cl, OH HO. 1) KMNO,/H,O/ NAOH/25 °C 2) H3O*
Which is the major isolated organic product of this reaction sequence? C B C₂H₂ C3H₂ 1. NaNH, 2. CHI;Br 3. Lindlar's cat., [₂ 4. mcpba (B) C₂H₂ (D) C3H7¹
19. Predict the product for the following reaction 20. Predict the product for the following reaction sequence. sequence. excess NH3 SOCI₂ 1. CH3CH₂MgBr 2. H3O+ _ ==>> A. B. C. D. IV E. OH Na₂Cr₂O7/H₂SO4/H₂O SOCI₂ V IV H || V HO NH₂ NH₂ ||| ABCDE A. B. D. E. IV I <<=== Br Mg/ether NHCH3 || excess SOCI₂ CH3NH2 1. CO2 2. H3O+ Pyridine NHCH3 NHCH3 V NHCH3 NH

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3./4/5./6. () Predict the major organic product(s). No mechanisms needed. CN HO, CN CN 1. LIAIH 2. H'H₂0 MgCl 1. 2. H'/H₂O 1. NaOH, H₂O 2. H H₂O' H₂O