3. Traces of heavy metals, such as Cu* and Pb²*, in water bodies can be separated through fractional precipitation. A research work investigates the use of NaOH(aq) in separating these two ions in a 1.00 L of water sample that contains 12.70 mg Cu²* (MM = 63.546 g/mol) and 39.90 mg Pb2* (MM = 399.32 g/mol). Given: Hydroxide of Ksp Cu²+ 2.20 x 10-20 Pb2+ 1.20 × 10-15 A. Write the balanced chemical equation and the corresponding Ksp expression for the dissolution of the hydroxide salt of (a) Cu²* and of (b) Pb²* in water. B. Calculate the molar solubility of the hydroxide salt of (a) Cu²* and (b) Pb²* in water. If NaOH(aq) is added gradually to the water sample, which of the two ions is more likely to precipitate first? Explain your answer. C. Calculate the initial molar concentration of each of the heavy metal ions in the water sample.

Chemistry
9th Edition
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Steven S. Zumdahl
Chapter4: Types Of Chemical Reactions And Solution Stoichiometry
Section: Chapter Questions
Problem 105AE: Chlorisondamine chloride (C14H20Cl6N2) is a drug used in the treatment of hypertension. A 1.28-g...
icon
Related questions
Question
3. Traces of heavy metals, such as Cu²* and Pb²*, in water bodies can be separated through fractional
precipitation. A research work investigates the use of NaOH(aq) in separating these two ions in a 1.00 L of
water sample that contains 12.70 mg Cu²* (MM = 63.546 g/mol) and 39.90 mg Pb²* (MM = 399.32 g/mol).
Given:
Hydroxide of
Ksp
Cu2+
2.20 × 10-20
Pb2+
1.20 x 10-15
A. Write the balanced chemical equation and the corresponding Ksp expression for the dissolution of the
hydroxide salt of (a) Cu²* and of (b) Pb²* in water.
B. Calculate the molar solubility of the hydroxide salt of (a) Cu²* and (b) Pb²* in water. If NaOH(aq) is
added gradually to the water sample, which of the two ions is more likely to precipitate first? Explain
your answer.
C. Calculate the initial molar concentration of each of the heavy metal ions in the water sample.
D. Calculate the equilibrium concentration of NaOH(aq) that must be exceeded to initiate the precipitation
of the less soluble metal hydroxide.
E. How much of the first metal ion is left in the solution when the second ion starts to precipitate? Express
your answer in percentage (%).
Transcribed Image Text:3. Traces of heavy metals, such as Cu²* and Pb²*, in water bodies can be separated through fractional precipitation. A research work investigates the use of NaOH(aq) in separating these two ions in a 1.00 L of water sample that contains 12.70 mg Cu²* (MM = 63.546 g/mol) and 39.90 mg Pb²* (MM = 399.32 g/mol). Given: Hydroxide of Ksp Cu2+ 2.20 × 10-20 Pb2+ 1.20 x 10-15 A. Write the balanced chemical equation and the corresponding Ksp expression for the dissolution of the hydroxide salt of (a) Cu²* and of (b) Pb²* in water. B. Calculate the molar solubility of the hydroxide salt of (a) Cu²* and (b) Pb²* in water. If NaOH(aq) is added gradually to the water sample, which of the two ions is more likely to precipitate first? Explain your answer. C. Calculate the initial molar concentration of each of the heavy metal ions in the water sample. D. Calculate the equilibrium concentration of NaOH(aq) that must be exceeded to initiate the precipitation of the less soluble metal hydroxide. E. How much of the first metal ion is left in the solution when the second ion starts to precipitate? Express your answer in percentage (%).
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Stoichiometry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781133611097
Author:
Steven S. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry for Engineering Students
Chemistry for Engineering Students
Chemistry
ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning