(3) In a titration, the % analyte is computed from the following equation: Vol (titrant) x M (titrant) x MW (analyte) % analyte = x 100 Weight (sample) Calculate the absolute error in the % analyte from the following data. Vol (titrant)= 38.04 t 0.02 ml M (titrant) MW (analyte) = 74.116 t 0.005 mg/mmol Wt (sample) = 800.0 t 0.2 mg = 0.1137 ± 0.0003 mmol/ml

(3) In a titration, the % analyte is computed from the following equation: Vol (titrant) x M (titrant) x MW (analyte) % analyte = x 100 Weight (sample) Calculate the absolute error in the % analyte from the following data. Vol (titrant)= 38.04 t 0.02 ml M (titrant) MW (analyte) = 74.116 t 0.005 mg/mmol Wt (sample) = 800.0 t 0.2 mg = 0.1137 ± 0.0003 mmol/ml

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter17: Electrochemistry

Section: Chapter Questions

Problem 80AP

See similar textbooks

Similar questions

You are preparing a 100.0 mL standard solution needed for titration analysis. The NaOH (40 g/mol) pellets are measured to be 0.5341 g in a balance with acceptable uncertainty of +0.001 g. Mass of the pellets is recorded after taring the container. The pellets are put in a beaker and added with 50 ml distilled water measured by a graduated cylinder. The solution is then quantitatively transferred to a 100-mL volumetric flask with uncertainty of ±0.08 mL and diluted to a 100-mL mark. What is the concentration (M) of the solution and estimate its uncertainty by propagation? Assumption: There is no uncertainty in molar mass. Express your answer as C+/- u M.
The organic base, tris-(hydroxymethyl)aminomethane (or simply TRIS or THAM) is an excellent primary standard. A 0.2486 g sample of the primary standard grad TRIS, (CH2OH)3CNH2 (M.M. = 121.14) was dissolved in distilled water and required 24.88 mL of a hydrochloric acid solution. Calculate the molarity of the solution
Exactly 10.00-mL aliquots of a solution containing phenobarbital were measured into 50.00-mL volumetric flasks and made basic with KOH. The following volumes of a standard solution of phenobarbital containing 2.000μg/mL of phenobarbital were then introduced into each flask and the mixture was diluted to volume: 0.000, 0.500, 1.00, 1.50, 2.00 mL. The fluorescence of each of these solutions was measured with a fluorimeter, which gave values of 3.26, 4.80, 6.41, 8.02, 9.56, respectively. a. plot the data. b. derive a least squares equation for the data plotted in (a). c. find the concentration of phenobarbital from the equation in (b). d. calculate a standard deviation for the concentration obtained in (c).
A STOCK SOLUTION containing 0.1581 g/L K2CrO4 was prepared.In order to make the CALIBRATION STANDARD, 5 ml of the STOCK was transferredinto a 50ml volumetric flask and then diluted with an appropriate solvent.Calculate:(a) The ppm of K2CrO4 in the CALIBRATION STANDARD.(b) The molarity of K2CrO4 in the CALIBRATION STANDARD. (c) Calculate the molar absorptivity of K2CrO4 (at 371.0 nm). Assume that Beer's Law isobeyed over this concentration range.At 371.0 nm, this CALIBRATION STANDARD in a cell of path length 1.00 cm gave a %T of 59.752.
Hydrogen peroxide solutions can easily be decomposed by dust, trace amounts of metals or light. It istherefore necessary to periodically determine the purity of the peroxide solutions.This can be done via a redox titration as follows: The density of a particular surgical grade hydrogen peroxide solution is 1.11g.cm-3. Exactly 10 mL of this solution was pipetted and quantitatively transferred, along with a sufficientamount of a dilute sulphuric acid solution, into a 250.00 mL volumetric flask and made up to the mark. A 25.00 mL portion of this diluted solution is pipetted into a conical flask, and titrated with a0.372 M KMnO4 solution. The endpoint of the titration is determined when the colourless solution in the conical flask turns apersistent bright pink due to the presence of excess permanganate ions. The average titration value is 26.20 mL of the KMnO4 solution 1.Determine the percentage of the hydrogen peroxide in the solution sample.2. Naturally occurring manganese…
A solution of HCl was titrated against sodium carbonate. What is the normality of acid for Trial 3 in the given data? T1 T2 0.3562 0.3479 0.3042 Weight (g) Initial V (mL) 0.80 1.60 0.40 Final V (mL) 35.20 36.70 39.80 Vol HCI used (ml) 35.10 39.40 N of HC (eq/L) 0.1954 0.1870 Average N of HCl (eq/L)
Sodium carbonate is a reagent that may be used to standardize acids in the same way that you have used KHP in this experiment. In such a standardization it was found that a 0.498-g sample of sodium carbonate required 24.8 mLmL mL of a sulfuric acid solution to reach the end point for the reaction. Na2CO3(aq)+H2SO4(aq)→H2O(l)+CO2(g)+Na2SO4(aq)Na2CO3(aq)+H2SO4(aq)→H2O(l)+CO2(g)+Na2SO4(aq) What is the molarity of the H2SO4H2SO4?
A 0.1475-M solution of Ba(OH)2 was used to titrate the acetic acid (60.05 g/mol) in a dilute aqueous solution. The following results were obtained. (See attached image)(a) Calculate the mean w/v percentage of acetic acid in the sample.(b) Calculate the standard deviation for the results.(c) Calculate the 90% confidence interval for the mean.(d) (d) At the 90% confidence level, could any of the results be discarded?
1)Please express the normal salt (NaCl) concentration in body fluid into molarity (mM).2) Commercial fuming Sulphuric acid (Oleum-H2S2O6) is 99.9%. solution. Please convert it into molarity.3) Find out the Volume (dm3) of product (gas) at RTP when 0.58 M, 150 mL NaOH (aq.) reacts with 350 mL, 0.25 NH4Cl.4) The above reaction has the product Ammonia, which when dissolved in 650 mL ethanol makes an alkaline ethanolic solution. Find its molarity (M) 5) Calculate the adult dose as per the BW of the baby. (Child dose-50 mg and the BW of the baby is 48 lb (British pound) (1lb=0.453 Kg)
A solution of HCl was titrated against sodium carbonate. What is the average normality of acid in the given data? (MW Na₂CO3 = 106) T2 0.3479 0.3562 0.3042 Weight (g) Initial V (ml) 0.80 1.60 35.20 36.70 39.80 Final V (mL) Vol HCl used (mL) 35.10 39.40 N of HCl (eq/L) 0.1954 0.1870 Average N of HCl (eq/L)
A 25mL volumetric pipet is used to deliver a sample of the stock solution marked “0.6000M X2SO4” into a 100mL volumetric flask. Distilled water is added to the flask until it is about 3/4thfull, the solution is mixed well, then more water is added to fill it up to the calibration mark, then it is mixed again. Calculate the concentration of X+ion in the dilute solution made above.
We want to determine the purity of alum sample bought in a local pharmacy in Miagao. A Chem 28 student determined the purity gravimetrically of a sample of alum, K2SO4:Al2(SO4)3:24H20. A 1.5879-g sample was dissolved and the aluminum precipitated as Al(OH)3. The precipitate was collected by filtration, washed, and ignited to give a product Al203 weighing 0.1572 g. Show your calculation to determine the purity of the alum sample.