3) Calculate the standard Gibbs energy of the following reaction at 298 K: CH₂COOH (1)→ CO (g) + CH₂OH (1) Hint: First, calculate the standard reaction enthalpy A,H and the standard reaction entropy AS using standard entropies and enthalpies of formation of compounds in the Data Section. Then, calculate the standard Gibbs energy of this reaction.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter13: Spontaneous Processes And Thermodynamic Equilibrium
Section: Chapter Questions
Problem 22P: Use data from Appendix D to calculate the standardentropy change at 25°C for the reaction...
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3) Calculate the standard Gibbs energy of the following reaction at 298 K:
CH₂COOH (1)→ CO (g) + CH3OH (1)
Hint: First, calculate the standard reaction enthalpy AH and the standard reaction entropy
AS using standard entropies and enthalpies of formation of compounds in the Data Section.
Then, calculate the standard Gibbs energy of this reaction.
Cadmium (Continued)
Cdo(s)
CaCO,(s)
Caesium (cesium)
Cs(s)
Cs(g)
Cs' (aq)
Calcium
Ca(s)
Ca(g)
Ca (aq)
CIO(8)
CaCO,(s) (calcite)
CaCO,(s) (aragonite)
CaF₂(s)
CaCl₂(8)
CaBry(s)
M/(g mol-¹)
C₂(g)
CO(g)
CO₂(g)
128.40
172.41
132.91
132.91
132.91
40.08
40.08
40.08
56.08
100.09
100.09
78.08
110,99
199.90
AH/(kl mol-¹)
-258.2
-750.6
0
+76.06
-258.28
0
+178.2
-542.83
-635.09
-1206.9
-1207.1
-1219.6
-795.8
-682.8
0
+1.895
+716.68
+831.90
-110.53
-393.51
413 on
Carbon (for 'organic' compounds of carbon, see Table 2.5)
C(s) (graphite)
12.011
C(s) (diamond)
12.011
C(g)
12.011
24.022
28.011
44,010
14010
AGKJ mol¹)
-228.4
-669 A
0
+49.12
-292.02
0
+1443
-553.58
-604.03
-1128.8
-1127.8
-1167.3
-748,1
-663.6
0
+2.900
+671.26
+775.89
-394.36
105 00
$20K molt
54.8
92.5
85.23
175.60
+133.05
41.42
154.88
-53.1
39.75
92.9
88.7
68.87
104.6
130
5.740
2.377
158.10
199.42
197.67
213.74
1176
CK¹mot')
43.43
32.17
20.79
-10.5
25.31
20.786
42.80
81.88
81.25
67.03
72.59
8.527
6.113
20.838
43.21
29.14
37.11
Transcribed Image Text:3) Calculate the standard Gibbs energy of the following reaction at 298 K: CH₂COOH (1)→ CO (g) + CH3OH (1) Hint: First, calculate the standard reaction enthalpy AH and the standard reaction entropy AS using standard entropies and enthalpies of formation of compounds in the Data Section. Then, calculate the standard Gibbs energy of this reaction. Cadmium (Continued) Cdo(s) CaCO,(s) Caesium (cesium) Cs(s) Cs(g) Cs' (aq) Calcium Ca(s) Ca(g) Ca (aq) CIO(8) CaCO,(s) (calcite) CaCO,(s) (aragonite) CaF₂(s) CaCl₂(8) CaBry(s) M/(g mol-¹) C₂(g) CO(g) CO₂(g) 128.40 172.41 132.91 132.91 132.91 40.08 40.08 40.08 56.08 100.09 100.09 78.08 110,99 199.90 AH/(kl mol-¹) -258.2 -750.6 0 +76.06 -258.28 0 +178.2 -542.83 -635.09 -1206.9 -1207.1 -1219.6 -795.8 -682.8 0 +1.895 +716.68 +831.90 -110.53 -393.51 413 on Carbon (for 'organic' compounds of carbon, see Table 2.5) C(s) (graphite) 12.011 C(s) (diamond) 12.011 C(g) 12.011 24.022 28.011 44,010 14010 AGKJ mol¹) -228.4 -669 A 0 +49.12 -292.02 0 +1443 -553.58 -604.03 -1128.8 -1127.8 -1167.3 -748,1 -663.6 0 +2.900 +671.26 +775.89 -394.36 105 00 $20K molt 54.8 92.5 85.23 175.60 +133.05 41.42 154.88 -53.1 39.75 92.9 88.7 68.87 104.6 130 5.740 2.377 158.10 199.42 197.67 213.74 1176 CK¹mot') 43.43 32.17 20.79 -10.5 25.31 20.786 42.80 81.88 81.25 67.03 72.59 8.527 6.113 20.838 43.21 29.14 37.11
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