28. A new compound is synthesized and found to be a monoprotic acid with a molar mass of 248 g/mole. When 0.0050 moles of this acid are dissolved in 0.500 L of water, the pH is measured as 2.94 What is the pK, of this acid? (A) (B) (C) (D) 2.33 3.89 5.78 7.78 29. What is the hybridization of carbon 1 (far left) and carbon 2 (middle) in this hydrocarbon: CH;CH=CH2? (A) sp?, sp (B) sp², sp? (C) sp?, sp? (D) sp, sp?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions
Section19.5: Nucleophilic Addition Of H2o: Hydration
Problem 8P: The oxygen in water is primarily (99.8) 16O, but water enriched with the heavy isotope 18O is also...
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но
HO
HO
HO
0 + ½ O, →
+ H,0
H
H
но
он
ascorbic acid
dehydroascorbic acid
Vitamin C is oxidized slowly to dehydroascorbic acid by the oxygen in air. It is catalyzed by ions such as
Cu*2 and Fe*3. The reaction can be followed by measuring the ultraviolet absorbance at 243 nm.
Time (hours)
Absorbance (A)
1/A
In A
- In A
0.75
1.3
-0.29
0.29
1
0,38
2.6
-0.97
0.97
2
0.19
5.3
- 1.7
1.7
3
0.095
11
- 2.4
2.4
28. A new compound is synthesized and found to be a monoprotic acid with a molar mass of 248
g/mole. When 0.0050 moles of this acid are dissolved in 0.500L of water, the pH is measured as 2.94.
What is the pKa of this acid?
(A)
(B)
(C)
(D)
2.33
3.89
5.78
7.78
29. What is the hybridization of carbon 1 (far left) and carbon 2 (middle) in this hydrocarbon:
CH3CH=CH2?
(A) sp³, sp
(B) sp?, sp?
(C) sp³, sp?
(D) sp, sp?
Transcribed Image Text:но HO HO HO 0 + ½ O, → + H,0 H H но он ascorbic acid dehydroascorbic acid Vitamin C is oxidized slowly to dehydroascorbic acid by the oxygen in air. It is catalyzed by ions such as Cu*2 and Fe*3. The reaction can be followed by measuring the ultraviolet absorbance at 243 nm. Time (hours) Absorbance (A) 1/A In A - In A 0.75 1.3 -0.29 0.29 1 0,38 2.6 -0.97 0.97 2 0.19 5.3 - 1.7 1.7 3 0.095 11 - 2.4 2.4 28. A new compound is synthesized and found to be a monoprotic acid with a molar mass of 248 g/mole. When 0.0050 moles of this acid are dissolved in 0.500L of water, the pH is measured as 2.94. What is the pKa of this acid? (A) (B) (C) (D) 2.33 3.89 5.78 7.78 29. What is the hybridization of carbon 1 (far left) and carbon 2 (middle) in this hydrocarbon: CH3CH=CH2? (A) sp³, sp (B) sp?, sp? (C) sp³, sp? (D) sp, sp?
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