27) Hydrolysis of an ester:OIICH,-C-O-CH2-CH2-CH, + H2028) Acid/ Base reaction of an amineCH3-CH2-NH2 H2CO329) Hydrolysis of an amide11CH3-CH2-CH2-CH2-CH2-C-NH-CH2-CH2-CH, + H20OMIC Molecules

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Answered: 27) Hydrolysis of an ester: O II…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

ChapterNW3: Nomenclature Worksheet 3: Benzene Derivatives

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MONTR Cryahoga Commnity College 27) Hydrolysis of an ester: O II CH,-C-O-CH,-CH,-CH,+ H,O 28) Acid/ Base reaction of an amine CH3-CH2-NH, + H2CO3 29) Hydrolysis of an amide O II CH3-CH2-CH2-CH2-CH2-C-NH-CH2-CH2-CH, + H20
28) Acid/ Base reaction of an amine CH,-CH2-NH2 + H2CO3 29) Hydrolysis of an amide II CH,-CH2-CH2-CH2-CH2-C-NH-CH,2-CH2-CH, + H20 AUTO
1 2 3 4 5 6 Cr₂O3 Base RX KNO3 H₂SO4 4 5- Isatoic Nitroisatin anhydride carbonyl O N- Alkyl isatin compound HCI/Zn 2 3 quinoline 4- carboxyl acid
OPh OPh D CI Br N E N Но o-SiMeg OH OPh OPh F NH2 Но N Но OH OH A V ( Choose ] Bu4N+ F- МСРВА (Ваyer villager) Mg, then CO2 (Kobe!!!!) NH3 (SNAR) H2S04, Heat (Fisher esterification) 03, DMS (ozonalysis) Choose (Choose ) E [ Choose ) F [ Choose ) B.
CH, C-OH CH;CH,-NH, + A product of the reaction above would be a(n) alkene salt secondary amine O aldehyde
H3C- H3C. OH XT H Et H2N–CH2CH3 It is difficult to prepare an amide from a carboxylic acid and an amine directly, since an acid-base reaction occurs which renders the amine nitrogen non-nucleophilic. Typically, in such an amide synthesis, the carboxylic acid OH group is first transformed into a better, nonacidic leaving group. In practice, amides are often prepared by treating the carboxylic acid with dicyclohexylcarbodiimide (DCC). The amine is then added and nucleophilic acyl substitution occurs easily because dicyclohexylurea is a good leaving group. This method of amide bond formation is a key step in the laboratory synthesis of peptide bonds (amide bonds) between protected amino acids. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions +N. H DCC alb :A alo H3C H3C CH₂CH3 Et H-A
Draw The Structures? Q 2-Acetylbenzoic acid (aspirin; acetylsalicylic acid) 1,5,5-Trimethylcyclopentene- 2-carboxylic acid (B-campholytic acid) 2,4-Hexadienoic acid (sorbic acid) 63-Phenylpropynoic acid
Draw the organic product(s) for each of the following reactions. If there is more than one product likely indicate the major. Be sure and show any stereochemistry.
anthanoid senies Ce Pr Nd Pm Sm Eu Gd Tb Yb Lu Dy 99 Но Er Tm 91 90 actinoid series 7 Th 92 93 94 95 96 97 98 100 101 102 103 Pa Np Pu Am Cm Bk Cf Es Fm Md No Lr D Question 36 Consider this reaction with the following value of dHo and answer the following question N2 (g) + 3H2 (g) → 2NH3 (g) dH° = -100 kJ Which of the following represents the dH° value of the decomposition reaction? O +100 kJ O -100 kJ O + 50 kJ O - 50 kJ • Previous No new data to save. Last checked at 10 DII 4x PriScn Ho % 21 R.
(b) Cortisone OH H2C CH -HO- H3C Oalcohol O carbon-carbon double bond Oester Oaldehyde Ocarbon-carbon triple bond Oether O amide Ocarboxylate anion Oketone Oamine O carboxylic acid O thiol (c) Prostaglandin PGE2 COOH Но OH Oalcohol O carbon-carbon double bond Oester Oaldehyde Ocarbon-carbon triple bond Oether Oketone O amide O carboxylate anion Oamine Ocarboxylic acid O thiol
Complete the given reactions by drawing the structures of the major organic products: Please draw the completed reaction OH HO HOCN H₂N H₂O H3PO4 OH HO HO. (excess) H3O+ H2SO4 H*
HO HO. OH base CI EIO- C-OEt epichlorohydrin OH NaOEt 2,6-dihydroxy- acetophenone *Na O2C. .CO2 Na* NaOH, H2O II OH Cromolyn sodium Cromolyn sodium, developed during the 1960s, has been used to prevent allergic reactions primarily affecting the lungs, as, for example, exercised- induced emphysema. It is thought to block the release of histamine, which prevents the sequence of events leading to swelling, itching, and constriction of bronchial tubes. v Cromolyn sodium is synthesized in the above series of steps. rch 31% 11:24 P 4/20/20-

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27) Hydrolysis of an ester: O II CH,-C-O-CH2-CH2-CH, + H20 28) Acid/ Base reaction of an amine CH3-CH2-NH2 H2CO3 29) Hydrolysis of an amide 11 CH3-CH2-CH2-CH2-CH2-C-NH-CH2-CH2-CH, + H20 OMIC Molecules