22.46 Draw the product formed when pentanoyl chloride (CH;CH,CH,CH,COCI) is treated with each reagent. a. H,O, pyridine b. CH;CH,OH, pyridine c. CH;CO0 d. NH; (excess) e. (CH;CH),NH (excess) f. CgH;NH, (excess) ANSWERS

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter18: Functional Derivatives Of Carboxylic Acids
Section: Chapter Questions
Problem 18.30P: Nicotinic acid, more commonly named niacin, is one of the B vitamins. Show how nicotinic acid can be...
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Explain and show step by step how did the product formed when pentanol is treated with reagents in letter C and F only. this is about carboxylic acid and its derivative.

22.46 Draw the product formed when pentanoyl chloride (CH;CH,CH;CH,COCI) is treated with each reagent.
a. H¿0, pyridine
b. CH¿CH;OH, pyridine
c. CH,COO"
d. NH3 (excess)
e. (CH;CH,),NH (excess)
f. CgH;NH2 (excess)
ANSWERS
22.46
CH3CH2CH2CH,COCI
H20
NH3
d.
CH;CH,CH,CH,CONH, + NH, C
а.
CH;CH2CH2CH,COOH +
excess
pyridine
+
(CH3CH2)2NH
CH;CH,OH
CH;CH2CH,CH2CON(CH2CH3)2
b.
CH;CH2CH2CH,COOCH,CH3 +
е.
excess
pyridine
+ (CH;CH2)2NH2 CF
CeH;NH2
CH;COO-
С.
f.
CH;CH,CH,CH,CONHC;H5
CH;CH2CH2CH2
`CH3
+ CF
excess
+
+ CgH5NH3 CI-
Transcribed Image Text:22.46 Draw the product formed when pentanoyl chloride (CH;CH,CH;CH,COCI) is treated with each reagent. a. H¿0, pyridine b. CH¿CH;OH, pyridine c. CH,COO" d. NH3 (excess) e. (CH;CH,),NH (excess) f. CgH;NH2 (excess) ANSWERS 22.46 CH3CH2CH2CH,COCI H20 NH3 d. CH;CH,CH,CH,CONH, + NH, C а. CH;CH2CH2CH,COOH + excess pyridine + (CH3CH2)2NH CH;CH,OH CH;CH2CH,CH2CON(CH2CH3)2 b. CH;CH2CH2CH,COOCH,CH3 + е. excess pyridine + (CH;CH2)2NH2 CF CeH;NH2 CH;COO- С. f. CH;CH,CH,CH,CONHC;H5 CH;CH2CH2CH2 `CH3 + CF excess + + CgH5NH3 CI-
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