20.77. The nitration of methanol, CH;OH, by nitrous acid is thought to proceed via the following mechanism: → CH;OH,* → CH;* + H,O CH;OH + H* - CH;OH,* CH,* + NO, → CH;NO, Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants?

Chemistry by OpenStax (2015-05-04)
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Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
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Chapter12: Kinetics
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Problem 21E: Alcohol is removed from the bloodstream by a series of metabolic reactions. The first reaction...
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20.77. The nitration of methanol, CH;OH, by nitrous acid is
thought to proceed via the following mechanism:
CH;OH + H+
CH;OH,*
CH;OH, *
→ CH;* + H,0
CH;* + NO,
→ CH;NO2
Suppose the first step is the RDS. What is the expected rate
law in terms of the original reactants?
Transcribed Image Text:20.77. The nitration of methanol, CH;OH, by nitrous acid is thought to proceed via the following mechanism: CH;OH + H+ CH;OH,* CH;OH, * → CH;* + H,0 CH;* + NO, → CH;NO2 Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants?
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