2. A spherical metallic nanoparticle of diameter d; = 100 nm melts at Tma = 900 K. A smaller spherical nanoparticle of the same metal, of diameter d2 = 50 nm, melts at Tm2 = 800 K. a) Explain why the smaller nanoparticle melts at a lower temperature. b) Calculate the melting point of the metal in bulk form.

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter8: Molecules And Materials
Section: Chapter Questions
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2. A spherical metallic nanoparticle of diameter di = 100 nm melts at Tmi = 900 K. A smaller
spherical nanoparticle of the same metal, of diameter dz = 50 nm, melts at Tm2 = 800 K.
a) Explain why the smaller nanoparticle melts at a lower temperature.
b) Calculate the melting point of the metal in bulk form.
Transcribed Image Text:2. A spherical metallic nanoparticle of diameter di = 100 nm melts at Tmi = 900 K. A smaller spherical nanoparticle of the same metal, of diameter dz = 50 nm, melts at Tm2 = 800 K. a) Explain why the smaller nanoparticle melts at a lower temperature. b) Calculate the melting point of the metal in bulk form.
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