5. Predict the outcome of the following reactionsCI MEOH, ElGNCI, AICI,b).HONH2H*ноHBrHOc)H*7. Predict the outcome of reactions of NaCN orMENH2 with each of the following substrates at0 °C and at 80 °C, rationalise your suggestion.d)OMe e)NMez 12. Suggest a reagent for the following reaction andprovide the mechanism?OHÖTBSÕTBS

Answered: Image /qna-images/answer/df7248b0-14e6-4c32-a8b8-85de45eca9b3.jpg

Answered: 12. Suggest a reagent for the following…

Science

Chemistry

12. Suggest a reagent for the following reaction and provide the mechanism ? OH OTBS ÕTBS

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: HO OH a 1. NH,NH, 2. КОН d. cs Scanned with CamScarner

A: The given compound is ketone. Ketone undergoes various types of reaction in presence of various…

Q: H-Br

A: The reaction taking place is given as,

Q: Provide the organic products of the following and also show the mechanism involved in (a)? (a)…

A: Wittig reagent (CH2=PPh3) has been used both the reaction .

Q: Give the major product (16) and the mechanism for the elimination reaction given below.

A: In this question, we will draw the major product with mechanism and explanation. You can see the…

Q: 8] Propose a mechanism to account for the following reaction H2SO4

A: Ethers are species that has a oxygen atom attached to two alkyl groups. Ethers are polar in nature…

Q: Conc. H2SO4 Но Br HBr a.

A: In a question carbocation is highly stable due to backbonding so Be add on that particular carbon…

Q: 18. Suggest a plausible mechanism with structures of the following reaction: Br, H,0 CH3 CH2B.…

A: In the reaction mechanism of the above reaction, first the alkene will attack on the Br2 molecule as…

Q: a) Provide a mechanism that accounts for the product formed in the following reaction. OH CH +…

A: In both the reactions, carbocation rearrangement takes place through hydride shift

Q: (d) Propose a reaction mechanism to account for the following reaction. AICI3

A: In this question we have to tell the mechanism of the given reaction.

Q: 4. Show the mechanism for the interconversion of the compounds below. Hint: They go through a…

A: In the presence of base acetone make enolate. Enolate acts as anucleophile and undergoes Michael…

Q: cess CHCH-C 1 KMKO, NaOH HO AICI, H$O. 2. H0

Q: oft انسار Eto Nat

A: Michael addition reaction: alpha , beta unsaturated esters undergo addition reaction when treated…

Q: 3. When compound 11 is treated with two equivalents of methansulfonic acid (MSOH) in…

A: The reaction involves 2 molecules of 11 as reactant. The reaction mechanism is drawn below.

Q: 4. Propose a plausible mechanism for the Wittig reaction and then the enol ether hydrolysis. ( H,C-O…

A: Since, you have asking multiple questions, so I will solved first question for you. You can see…

Q: 4) Predict the products of the ff reagents upon ozonolysis (oxidative-work up): В. A.

A: Ozonolysis is the process by which ozone (O3) reacts with alkenes (olefins) to break the double bond…

Q: H₂SO4 OH

A: mechanism of the formation of the following compound, and an alternative product that could be…

Q: What is the predominant mechanism of the reaction below?

A: Elimination reaction : Inpresence of strong base , heating conditions elimination reactions…

Q: Provide a detailed step-by-step mechanisms for the reaction shown. CH;CH2SH + Br, + NaOH

Q: + K H + H H₂N 'M H •R (S)-proline (cat.) DMSO R Z

A: It is the amino alkylation of an enolisable cabonyl compound in acidic conditions with the help of…

Q: HCIO4 Br2 MECO2H Br

Q: 7. Write the structures for A and B in the following synthesis scheme. Also, write a detail…

A: In this question we have to tell the product of the reaction and also its mechanism.

Q: Complete the following syntheses by providing the reagents and conditions at the reaction arrows.…

A: 1. Friedl craft's alkylation : alkylation of benzene, -Br group is ortho/para directing group…

Q: Propose a mechanism for this isomerization. ARSO3H

A: Any molecule or ion which are electron-rich species is called nucleophile, for example -NH2,-OH, and…

Q: Trimethyl Phosphite reacts with bromomethane to afford the product shown below via a two-step…

Q: (ORGANIC CHEMISTRY) (mechanisms) please give a answer for the following mechanism. Provide a…

A: Given reaction,

Q: Alkyl diazonium salts decompose to form carbocations, which go on to form products of substitution,…

A: Applying concept of elimination, and rearrangement reaction based on appropriate stereochemistry of…

Q: 3. Show how you could efficiently synthesize the products in (a) and (b) from the assigned starting…

A: Ans is given as follows

Q: 2. Draw a detailed mechanism for the following reaction and give the structure of the product. NH2…

Q: Provide a detailed mechanism for the following reactions and determine the major product: 14. a) b)…

Q: но H2SO4,Heat

Q: 6. Provide the full mechanism for the Friedel-Crafts Acylation reaction in the first step of the…

Q: Propose a detailed mechanism for the reaction below. لعلام , AICI3

Q: 3) Provide a detailed mechanism for the illustrated transformation. Use three-dimensional…

A: This is an example of Pummerer rearrangement

Q: For the compound below, propose an efficient synthesis using diethyl as a starting material. Provide…

Q: aq Br2

A: Given reaction is bromination reaction. When alkene reacts with aqueous bromine , bromo alcohol is…

Q: HCIO4 Br2 MECO2H

A: 1- In the first reaction, Keto form converted into enol form in acidic medium and then enol form is…

Q: The acid-catalyzed hydration of the compound below gave three products. Please provide a detailed…

A: Any molecule or ion which are electron rich species are called nucleophile for example -NH2,-OH and…

Q: R + CO2 or hv An acyl peroxlde Using this information, provide a mechanism of formation for each of…

A: Hint: Free radical are formed by the homolytic fission of covalent bond. Accordingly, one electron…

Q: 3. Propose a mechanism for the following reaction sequence. Et 1. BuLi, 2 moles 2. CH3CH2Br Ph

A: The reaction proceeds with a nucleophilic addition elimination reaction mechanism at the carbonyl…

Q: 7. Provide the full mechanism for the Friedel-Crafts Alkylation reaction in the third step of the…

Q: Provide the best combination of reagents for the following transformation. NMe NME2 O 1. H+,…

Q: Question is attached

A: According to Berdt's rule it is observed that a double bond or a charge is highly unstable at bridge…

Q: 5. When the starting material below is treated with benzoyl chloride and a catalytic quantity of…

A: We’ll answer the first question since the exact one wasn’t specified. Please submit a new question…

Q: provide the mechamism and tell the name of each reaction d. КОН / Н20 е. 2 ~OH H30*

A: d. Aldol condensation:The alpha hydrogen of carbonyl compounds is acidic in nature and it is removed…

Q: V(CO)6 undergoes CO substitution by an associative mechanism. explain and show the complete…

Q: 5.9. Suggest mechanisms that account for the outcome of the following reactions: а. Si(CH3)3 1) Br2,…

A: As per the rules only first three sub-parts can be answered: Organic reaction mechanism.

Q: 7.Which mechanism would account for the product shown?

A: Mechanism of the elimination reaction.

Q: Propose a mechanism for this reaction. CI + Cl2 + HCI CH3COOH (racemic)

A: The given chemical reaction is written as,

Q: 5.1. Suggest a mechanism for the following transformation and say how you would test it. CI CI OC…

A: The given substrate is an organometallic complex in which the central metal is iridium (Ir). Let us…

Q: 3) Write a detailed mechanism of: CH. CH HNOT HYSO! "NO.

A: Given is the reaction between Toluene in presence of nitric acid and sulfuric acid.

Concept explainers

Sulfur Functional Groups

Many organic molecules contain sulfur functional groups and have their own importance in chemistry as well as biology. Some of the organic molecules which contain sulfur functional groups and the corresponding sulfur functionality is given below:

Question

5. Predict the outcome of the following reactions
CI MEOH, ElGN
CI, AICI,
b)
.HO
NH2
H*
но
HBr
HO
c)
H*
7. Predict the outcome of reactions of NaCN or
MENH2 with each of the following substrates at
0 °C and at 80 °C, rationalise your suggestion.
d)
OMe e)
NMez

12. Suggest a reagent for the following reaction and
provide the mechanism
?
OH
ÖTBS
ÕTBS

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

12. What reaction occurs as a hydrochloric acid solution is added to a solution containing equal concentrations of acetic acid and sodium acetate? CH3COOH + H+ ⇋ CH3COOH2+ 2CH3COO– +2H+ ⇋CH3COO+H2 CH3COO– + H+ ⇋ CH3COOH CH3COOH + H+ ⇋ CH3CO+ + H2O CH3COOH + HCl ⇋ CH3COO– + H2Cl+
Which of the following reactions is/are feasible? NaNH, NH3 H3C H₂C CI OH O I and IV only O I, III and IV O I and II only Olonly SOCI₂ H3C NH₂ H3C CI NaCl || OH IV
4. Write the following sequence of reactions: Cact. t°C > A HNO3 conc. CH;CI В AICI13 3 H-CEC-H H2SO4 conc. Homework 2
21. Which of the following is the correct reaction intermediate? HCI, CH3OH Meo OMe intermediate НО Он нО ОМе OMe OH OMe a. b. C. d. e.
2. Predict the structure of the products (A-E) of the following reactions. BugSnH OMe AIBN Toluene, 80 "C OH 1) NaH, CS,, BnBr Ph B HO" 2) BuzSnH, AIBN H Toluene, 80 °C BuşSnH SPh AIBN Toluene, 80 "c 1) LDA, THF, -78 °C then PhSeBr D 2) H202 1) AIBN, SnBu, Me. Br E 2) O, then PPhg
H-CI II CH3NH2 N-CH3 II N-H ELOH H2SO, (cat) H2N OEt O a! Which of the following reactions will proceed as written? Ob." Oc II C. Odly II Oe. Todas proceden según están escritas. (All)
9 Complete the following reactions by briefly explaining in each case the type of reaction taking place. allo iii. iv. NOH TT. H₂SO4 A H₂O ??? ??? + ???
Which of the following reactions is /are feasible? NaNH2 NaCI H3C CI NH3 H3C NH2 II SOCI, OH H3C HO. H3C CI IV II O Tand II only O Tand IV only O Tonly O I, III and IV
Write the products structures and mechanisms CO2H A = N. H (cat.) HO (a) ? NC. CN OMe solvent Ph (i) (ii)
3. Write the product (s) formed in the following reactions. OH conc. HCI 1) DMSO/ (COCI), 2 eq/-60 °C 2) Et,N (excess) НО PCC/CH,Cl, OH HO. 1) KMNO,/H,O/ NAOH/25 °C 2) H3O*
3. A typical vitamin C tablet contains pure ascorbic acid H2C6H606 (a weak, diprotic acid). If 2 tablets are dissolved in about a cup of water, the resulting concentration of the ascorbic acid is 0.0115 M. a. Give the equation for the dissociation for the first ionization (loss of the first acidic arlt el todW b aiH broosz arit ot H). This ionization has a Ka of 8.00 x 10°. b. What is the equilibrium concentration for all species from the first ionization?
Choose the correct product for the given reaction, assume aqueous workup. Meli Br OH OH Br В. Br А. OLi D. Br С. Br O A Ов