11. Calculate the wavenumbers of the two highest energy vibrational transitions for the ¹271³5Cl molecule.[Note: For this molecule, the vibrational constant (v) is 384.3 cm¯¹, and the first order anharmonicityconstant (Xe) is 0.0039.]

11. Calculate the wavenumbers of the two highest energy vibrational transitions for the 1271³5Cl molecule. [Note: For this molecule, the vibrational constant (v) is 384.3 cm¹, and the first order anharmonicity constant (Xe) is 0.0039.]

11. Calculate the wavenumbers of the two highest energy vibrational transitions for the 1271³5Cl molecule. [Note: For this molecule, the vibrational constant (v) is 384.3 cm¹, and the first order anharmonicity constant (Xe) is 0.0039.]

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter12: Thermodynamic Processes And Thermochemistry

Section: Chapter Questions

Problem 62P

See similar textbooks

Related questions

Q: 5. a) Calculate the pH of the buffer solution made by mixing 200.0 mL of 0.100 mol/L acetic acid,…

Q: 6.) Estimate the freezing point of a 0.0100 molal aqueous solution of a.) K2CO3 b.) La (NO3)3.

A: To find out the freezing point of the solution, we need to use the formula which contains molality,…

Q: The mole fraction of NH3, N₂ and CH4 in a mixture of these 3 gases are 0.1,0.2 and z. respectively.…

Q: 1. Identify all of the Bronsted bases in the following reversible reaction: HIO3 + H₂O: HgO - 10 A…

A: The species which can accept proton or H+ ion from another species, is known as bronsted base.

Q: Write the following metals using Roman numeral notation. Then, explain why the Roman numeral differs…

Q: 13. The correct name for the following is A. Cyclobutane B. 1-Hexene C. I-Cyclohexene D Cyclohexane

A: All compounds have specific name , this is an organic compound. The given compound is cyclic and in…

Q: Which of the following pairs can be differentiated by lodoform Test? Ethanal and butyraldehyde None…

Q: Select the Single Replacement Reactions that WILL occur NaCl + H2 -> HCI + Na AgNO3 + Ca -> Ca(NO3)2…

A: Answer : Option 2 is correct for the first question. Its a single replacment reaction. Since you…

Q: Choose the chemical nitrogen oxide reactions below most likely to not be elementary reactions. N₂O4…

A: We have to tell among the given reaction which one is most likely not to be an elementary reaction.…

Q: (c) Draw curly arrow mechanisms to predict the products (G) and (H) of each of the reactions below.…

A: A) . Trialkyle silyle act as a protecting group of alcohol. B). Nucleophilic secondary amine will…

Q: (iv) Show both resonance canonical forms describing the bonding in enolate C. Use these diagrams to…

A: Since you asked specific question so as per Q&A guidelines of portal I solved part IV for other…

Q: The following reaction occurs at 298 K: Zn(s) + 2Ag+(aq) --> Zn2+(aq) + 2Ag(s). Calculate ∆G° and K…

A: Anode - Electrode where oxidation takes place Cathode - Electrode where reduction takes place…

Q: The work function for scandium is 5.61 x 10-19 J. Calculate the wave he lowest energy photon that…

A: In (iii) Given Work function = 5.61 ×10-19 J We have to find the wavelength of the photon which…

Q: Using 2-methoxy-3-methylhexanal, i) ii) answer the following questions: Does this molecule contain…

A: Since you have posted a question with multiple sub parts, we willprovide the solution only to the…

Q: (v) Provide a detailed mechanism for the Claisen reaction between S and T, and give the structure of…

A: We have to give the mechanism for the Claisen condensation reaction takes place between the compound…

Q: determine the plausible identity of the compound from the given possible compounds.

A: A question based on qualitative analysis. A set of possible compounds and another set of organic…

Q: (c) The kinetic energy, Ke, of electrons emitted from a metal surface after irradiation with UV…

A: Given that, The value of the Planck's constant is h = 6.626×10-34 J s. The value of the speed of…

Q: CH3COH [H] CH3CH₂CH₂NCH₂CH₂CH3 CH₂CH₂CH3 ? [H] ? + CH3CH₂CH₂CI BASE ?

A: Given reactions: We have to find the products of the reactions.

Q: Which of the following atoms can be used to fill a vacuum in a metal filament light bulb according…

A: Lewis’s structure: Lewis’s bonding theory is based on the octet rule. The Lewis structure is a…

Q: CH₂CH3 CH3CHCH₂CCH₂CH₂CH3 CH3CHCH2 SH CH₂CH3

A: To name a structure in organic chemistry, it is important to identify the longest carbon chain.

Q: CH3CHCH₂OCCH₂CHCH3 CH3 CH₂CH3

Q: 6. What volume of a 2.28 M aqueous sodium carbonate will completely react with 125 mL of 0.525 M…

A: Given data is Molarity of aqueous sodium carbonate = 2.28 M Molarity of aqueous Calcium chloride=…

Q: i.e. the of an electron being within a given location with respect to the nucleus.

A: The location of electrons in atoms is most accurately described in terms ....

Q: The particle on a ring is a useful model for the motion of electrons around the coronene ring. See a…

A: The coronene ring has been given to follow the particle in a ring model. The circular radius of the…

Q: 22) Pyridoxal pyrophosphate (PLP) can catalyze both a,ß-elimination reactions and B,y-elimination…

A: Pyridoxal phosphate: Pyridoxal phosphate is a small organic molecule and co-enzyme that helps the…

Q: A student was asked to draw the Lewis structure for CH20. Is the Lewis structure the student drew…

A: Lewis structure represents the valence shell electrons of each and every atom of the molecule.…

Q: An aqueous urea solution have an osmotic pressure of 20.5 atm at 35 °C. Calculate the amount of urea…

Q: this compound could be prepared from Fe2O3, how many moles of Fe2O3 would be needed to prepare 5.12…

A: Moles of Fe3O4 = 5.12 mole

Q: Student Marilou H₂N NH₂ O₂SH II NH₂ OH HSO₂ E III

A: Marilou has chosen suitable organic reagents to synthesize Trypan blue. By using Chicago red and…

Q: A chemical reaction that is first-order in X is observed to have a rate constant of 2.20 x 10–2 s–1.…

Q: (iii) During the conversion of G into F an undesired, isomeric, cyclopentenone also forms. Draw this…

A: Synthons- It is defined as a structural unit within a molecule that is formed by a possible…

Q: t a certain temperature, the reaction PCl5(g) PCl3(g) + Cl2(g) has an equilibrium constant…

A: The forward reaction is given as PCl5(g) <===> PCl3(g) + Cl2(g) ; Kc = 5.8 x 10-2 The…

Q: How many valence electrons must this atom lose to have a complete octet in its valence shell? 11…

A: The given atom has total 11 protons, 12 neutrons and 11 electrons. The name of this atom is sodium.

Q: What is the de Broglie wavelength of an electron traveling at a 3.61×106 m/s? m/s 1

A: de broglie wavelength, λ = h/mv

Q: The specific heat capacity of element Y is 0.8 cal/goC. If 40 calories of heat are added to 10 grams…

Q: What is the possible identity of the amine sample when subjected to Hinsberg test if the precipitate…

A: A question based on qualitative analysis. Based on the Hinsberg test for the distinction among…

Q: The Λm KCl(aq) 0.1 M at 298 K is 129 Scm2/mol. The resistance measured in a cell conductivity was…

A: The molar conductivity of the KCl = ΛmKCl = 129 Scm2/mol The molarity of the KCl = MKCl = 0.1 M The…

Q: identify the following compound with chemical methods CHO COOCH3 O CH3CCH₂COOCH₂CH3 (CH3)3CBr…

A: There are many way to differentiate all compound by oxidation method or SN1 OR SN2 mechanism.

Q: Draw the structure of 3,3-diethyl-4-methyl-1-hexyne

Q: B) 2 C) 3 4) What is the major product of the following reaction? Br NaOCH₂CH₂ A)…

A: NaOCH2CH3 is a strong base and it gives elimination reaction.

Q: What volume of 0.20mol/L acetic acid solution is needed tomake 100ml of 0.015mol/L acetic acid…

A: Since, Molarity is the number of moles of solute dissolve in one litre of the solution. Thus,

Q: Use the given reactions to answer question 4. Zn + Cu(NO3)2 → Zn(NO3)2 + Cu Zn + Pb(NO3)2 → Zn(NO3)2…

A: In displacement reaction, metal with higher reactivity or which is more reactive replaces the the…

Q: Show complete solutions with explanations. Calculate the ΔG° of the reaction below at 785 K. Is the…

A: To calculate the ΔG° of the reaction at 785 K, we can use the equation: ΔG° = ΔH° - TΔS° Where…

Q: 3. The heat of formation of methane at 298 K at constant pressure (ArH) is -74.78 kJ. Calculate its…

Q: ) 0₂ K EtO₂C L CO₂Et EtO₂C. EtO₂C M N Heating sulfone K generates, in equilibrium, butadiene L and…

Q: 4. Observables & Operators. State both classical-mechanical bbservables (i) Momentum (ii) Angular…

A: One of the postulate of quantum mechanics states that: " For every observable in classical…

Q: Allowing mixing of the two volumes, what is the change in entropy when the valve is opened? is A.S…

A: We need to fill the blanks using the entropy change decreases, increases or zero. This is related…

Q: Possible compounds: p-chlorobenzoic acid acetaldehyde trimethylamine styrene glucose Qualitative…

A: Clear solution of sodium fusion test indicates the absence of heteroatoms like halogens, nitrogen,…

Q: Answer and explain.

A: The given reaction is an example of Diels-Alder reaction. In the Diels-Alder reaction, the…

Q: (iv) Provide a detailed mechanism for the Claisen condensation reaction between L and M, and give…

A: iv) Claisen condensation reaction: The coupling reaction which results a beta-keto ester or a…

Question

11. Calculate the wavenumbers of the two highest energy vibrational transitions for the ¹271³5Cl molecule.
[Note: For this molecule, the vibrational constant (v) is 384.3 cm¯¹, and the first order anharmonicity
constant (Xe) is 0.0039.]

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step by step

Solved in 4 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Determine the number of total degrees of freedom and the number of vibrational degrees of freedom for the following species. a Hydrogen sulfide, H2S b Carbonyl sulfide, OCS c The sulfate ion, SO42 d Phosgene, COCl2 e Elemental chlorine, Cl2 f A linear molecule having 20 atoms g A nonlinear molecule having 20 atoms
Determine the number of total degrees of freedom and the number of vibrational degrees of freedom for the following molecules. a Hydrogen fluoride, HF b Hydrogen telluride, H2Te c Buckminsterfullerene, C60 d Phenylalanine, C6H5CH2CHNH2COOH e Naphthalene, C10H8 f The linear isomer of the C4 radical g The bent isomer of C4 radical.
3 Calculate the frequencies and wavelengths for the rotational transition J = 0 → J = 1 and J = 4 → J = 5 for the HCl molecule. The internuclear distance is Re = 0.12745 nm. What is the frequency shift between the two isotopomers H35Cl and H37Cl for the two transitions?
(hydrogen iodide, the superscripts represent the atomic mass number) (a) How fast will HI molecules rotate at the quantized rotational state with the rotational quantun number J of 2, given the bond length of 0.161 nim? (b) Calculate the effective force constant of the vibrational mode of HI at a wavenumber of 2300 cm' measured by infrared absorption spectrum. (c) HI has the bond energy of 3.06 eV. Applying the parabolic approximation to estimate the longest distance in which H and I atoms can be stretched before the dissociation of the molecular bond
Calculate the energy of the J=0 to J=1 rotational transition of the O₂ molecule with a bond length of 121 pm.
Explain why the lines in the spectrum for H35Cl and H37Cl give rise to different rotational constants for the two molecules.
The wavelength of the vibrational transition in the 79Br81Br molecule is3.09 × 10-5m. Calculate the force constant for the bond in this molecule.
The wavenumber of the fundamental vibrational transition of Cl 2 is 565 em·'. Calculate the force constant of thebond.