1. Predict the major product (or products) formed when each of the following reacts with Cl, and FeCl,. Then name the products (IUPAC or common) (a) Ethylbenzene (b) Anisole (methoxybenzene) (c) Fluorobenzene (d) Benzoic acid (e) Nitrobenzene (f) Chlorobenzene (g) Biphenyl (C,H,-C,H,) (h) Ethyl phenyl ether 2. Predict the major product (or products) formed when each of the following reacts with a mixture of concentrated HNO, and H,SO, (c) 4-Chlorobenzoic acid (d) 3-Chlorobenzoic acid (a) (e) Phenyl acetate Acetanilide Benzophenone

1. Predict the major product (or products) formed when each of the following reacts with Cl, and FeCl,. Then name the products (IUPAC or common) (a) Ethylbenzene (b) Anisole (methoxybenzene) (c) Fluorobenzene (d) Benzoic acid (e) Nitrobenzene (f) Chlorobenzene (g) Biphenyl (C,H,-C,H,) (h) Ethyl phenyl ether 2. Predict the major product (or products) formed when each of the following reacts with a mixture of concentrated HNO, and H,SO, (c) 4-Chlorobenzoic acid (d) 3-Chlorobenzoic acid (a) (e) Phenyl acetate Acetanilide Benzophenone

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Write equations showing how to prepare each of the following from benzene or toluene and any necessary organic or inorganic reagents. If an ortho, para mixture is formed in any step of your synthesis, assume that you can separate the two isomers. (a) Isopropylbenzene (b) p-Isopropylbenzenesulfonic acid (c) 2-Bromo-2-phenylpropane (d) 4-tert-Butyl-2-nitrotoluene (e) m-Chloroacetophenone (f) p-Chloroacetophenone (g) 3-Bromo-4-methylacetophenone (h) 2-Bromo-4-ethyltoluene (i) 3-Bromo-5-nitrobenzoic acid (j) 2-Bromo-4-nitrobenzoic acid (k) 1-Phenyloctane (l) 1-Phenyl-1-octene (m) 1-Phenyl-1-octyne (n) 1,4-Di-tert-butyl-1,4-cyclohexadiene
Write the structure of the major organic product formed in the reaction of 1-pentene with each of the following: (a) Hydrogen chloride (b) Dilute sulfuric acid (c) Diborane in diglyme, followed by basic hydrogen peroxide (d) Bromine in carbon tetrachloride (e) Bromine in water (f) Peroxyacetic acid (g) Ozone (h) Product of part (g) treated with zinc and water (i) Product of part (g) treated with dimethyl sulfide (CH3)2S
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1. (a) Oxidation of 1-butanol with PCC will produce which of the following? 2-chlorobutanal butanone butanoic acid butanal (b) Which synthetic route is the best way to prepare ethyl isopropyl ether? CH3CH2OH + (CH3)2CHOH + H2SO4, 140 oC CH3CH2ONa + (CH3)2CHOH CH3CH2ONa + (CH3)2CHBr (CH3)2CHONa + CH3CH2Br (c) The Williamson ether synthesis involves nucleophilic substitution involving an alkyl halide and an alcohol. (True or False)
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(b) acid, HNO3 to produce compound L. The reaction of compound L with bromine, Br2 in the presence of iron tribromide, FeBr3 produced compound M. Benzene also undergoes Fridel-crafts alkylation reaction with chloroethane, CH;CH2CI using catalyst N to produce compound P. Benzene, CeHe undergoes substitution reaction with concentrated nitric Benzena, CsHe menjalani tindak balas penukargantian dengan asid nitrik, HNO, pekat untuk menghasilkan sebatian L. Tindak balas sebatian L dengan bromin, Brz dengan kehadiran ferum tribromida, FeBrs menghasilkan sebatian M. Benzena juga menjalani tindak balas alkilasi Fridel-crafts dengan kloroetana, CH3CH2CI dengan menggunakan pemangkin N untuk menghasilkan sebatian P. (i) Draw the structural formula of L, M and P. Lukiskan formula struktur bagi sebatian L, M dan P. (ii) State catalyst N. Nyatakan pemangkin N. (iii) Show the formation of electrophile that will be reacted with benzene for the formation of compound P.
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(a) When (Z)-3-methylhex-3-ene undergoes hydroboration–oxidation, two isomericproducts are formed. Give their structures, and label each asymmetric carbon atomas (R) or (S). What is the relationship between these isomers?(b) Repeat part (a) for (E)-3-methylhex-3-ene. What is the relationship between the productsformed from (Z)-3-methylhex-3-ene and those formed from (E)-3-methylhex-3-ene?