1. Look at the spectrum shown and answer the following questions: 1.4 1.2 - 0.4 0.2 24n 280 320 Wavelength (nm) 200 220 260 300 340 360 380 Is the spectrum shown a band spectrum or line spectrum? а. b. If the concentration of the solution was 36 ppm, what is the absorptivity of the substance at 240 nm? Assume a path length of 1.0 cm. Absorbance
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- Chemistry please help me wt the ff: a. Calculate the concentration (g/mL) of acrolein [CH2=CHCHO] that should be prepared in orderto give an absorbance of 0.8 at 217 nm ( = 16,000). b. Propose a structure for C7H4O2Cl2, as an acid with λmax 242 nm. c. Describe briefly the steps in obtaining the spectrum of a sample using Thermo Scientific Nicolet IS5 FT-IR Instrument starting from loading the solid and liquid samples.2. The molar absorptivity of compound A & B were measured with pure solutions as follows: wavelength (nm) Ea (M'cm-') 2139 EB (M-'cm-') 8469 312 417 10892 4325 (a) Calculate the frequency at wavelength of 312 nm and 417 nm. What wavelength has the greatest frequency? What wavelength has the greatest energy (show your calculation)? (b) A mixture of compound A and B in a 1.00 cm cell had an absorbance of 0.543 at 312 nm and 0.762 at 417 nm. Find the concentrations of A and B in the sample. 3. Given the molar absorptivity of a pH indicator at 525 nm is 16884 M-'cm for In and 1125 M-'cm- for HIn, calculate the pKa of the indicator if the absorbance of a 8.40 X 105 M solution of the indicator at pH 5.48 is 0.412 using a 1.00 cm cell.Chemistry 1. Brifely explain what is meant by diamagnetic and paramagnetic shielding in NMR spectrocopy?
- A 1.0x10-3 M solution of a dye X shows an absorbance of 0.20 at 450 nm wavelength and an absorbance of 0.05 at 620 nm wavelength. Calculate the extinction coefficient for each wavelength. (1cm is the constant path length) (Ans. e450 = 200 ; e620 = 50)The points on the graph are used to depict the intensity of the ray detected. FT-IR spectrophotometers collect the interferograms of the sample and Fourier-transform them to an absorption spectrum and identify its band spectra analysis. Observe what you see in the graph.When measured in a 1.00 cm cuvette, a 4.1x10M solution of species X exhibited absorbances of 0.1025 and 0.533 at 530 nm and 325 nm, respectively. A8.20x10 M solution of species Y gave absorbances of 0.230 and 0.508 at 530 nm and 325 nm, respectively. Both species were dissolved in the same solvent, and the solvent's absorbance was 0.000 and 0.000 at 530 nm and 325 nm, respectively, in a 1 cm cuvette. Calculate the concentrations of X and Y in an unknown solution that yielded absorbance data of 0.683 at 530 nm and 1.351 at 325 nm in a 1.0 em cuvete O A.X-4.20 x10 M Y=3.20 x104 M OBX-1.25 X10M Y420 x10-SM OCX-3.75x1oM Y-1 A10M OD.X-3.80 x 10M Y=2.10x10M