1. chloro 3. Inductive effect 2. -CH₂CH₂CH₂C=CH Inductive effect :0: || –CH,CH,CH,CH=CH-C—QCH3 Resonance effect Resonance effect Inductive effect Resonance effect O
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- Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. 2. 3. NO₂ N Submit Answer CH3 -NO₂ -C=C-N(CH3)2 HH Inductive effect Inductive effect [References] Inductive effect Resonance effect Resonance effect Resonance effect Retry Entire Group 2 more group attempts remainingClassify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. ö 1. Inductive effect V Resonance effect ÖCH,CH3 :0: Inductive effect Resonance effect -CH,CH2CH,CH2OH Inductive effect Resonance effect -ö- -OCH,CH3 :ö: 2. 3.Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. 2. 3. - CHỊCH,CH2−NH :0: :0: --CCH₂CH₂CCH3 -OCH, CH2–C Inductive effect Inductive effect Inductive effect Resonance effect Resonance effect Resonance effect
- O || CH3-CO-C-CH3 tCH3CH2CH, NH CH 3 | CH3-C-CL + CH3-N-CH3 Complete the following reaction.CH3 to Br- -H + Nal • product; Sy2 product of the reaction is : Аcetone H- -CH3 CH2 – CH3 CH3 CH3 CH3 CH3 it it -H H- -CH3 (d) -CH3 -H- (а) H• (Ъ) H- -CH3 -CH3 (с) H- CH -H- ČH2 – CH3 ČH2 – CH3 CH2 – CH3 CH2- CH3 2.Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. 1. --CH2CH2CH2-N+ :0: 2. -C-OCH2CH₂OCH3 Inductive effe ✓ Inductive effect acceptor donor no effect Resonance effect Resonance effect 3. -N- -CH2CH3 Inductive effect Resonance effect ethylamino
- Alcohols are important for organic synthesis, especially in situations involving alkenes. The alcohol might be the desired product, or the OH group might be transformed into another functional group via halogenation, oxidation, or perhaps conversion to a sulfonic ester derivative. Formation of an alcohol from an alkene is particularly powerful because conditions can be chosen to produce either the Markovnikov or non-Markovnikov product from an unsymmetrical alkene. Using your reaction roadmap as a guide, show how to convert 4-methyl-1-pentene into 5-methylhexanenitrile. You must use 4-methyl-1-pentene and sodium cyanide as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.Explain the fact that the C-O stretch in ethers and esters occurs at 1000-1100 cm-1 when the C is sp hybridized, but at 1250 cm- when it is sp2 hybridized.Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. -C =C-N(CH3)2 Inductive effect Resonance effect H H 2. Inductive effect Resonance effect 3. :0: T -P :O: -N(CH3)2 Inductive effect Resonance effect
- Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 1. :0: || Inductive effect Resonance effect -CH=CH-C-OCH3 2. -C=C-N(CH3)2 Inductive effect Resonance effect H H 3. Inductive effect CEN: Resonance effect Submit Answer Retry Entire Group 2 more group attempts remainingClassify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d = donor n = no effect 2. 3. -P(CH3)3 trimethylphosphonium :0: + -S-CH3 CH3 -ÖCH3 Inductive effect Submit Answer Inductive effect Inductive effect Retry Entire Group Resonance effect Resonance effect Resonance effect 9 more group attempts remainingWhich of these products is the result of a hydride shift occuring during the substitution reaction of aqueous 2-chloro-3-methylpentane? CH3CH2CCH2CH3 || CH2 CH3CH(OH)CH(CH3)CH2CH3 CH2=CHC(CH3)=CHCH3 CH3CH=C(CH3)CH2CH3 CH3CH2C(CH3)CH2CH3 | OH