1. (a) Write as many chemically reasonable syntheses as you can think of for ethyl 2-methylpropyl ether (ethyl isobutyl ether). Be sure that at some point in one or more of your syntheses you utilize the following reagents (not all in the same synthesis, however): PBR3, SOCI2, p- toluenesulfonyl chloride (tosyl chloride), NaH, ethanol, 2-methyl-1-propanol (isobutyl alcohol), concentrated H2SO4, Hg(OAc)2, ethene (ethylene). (b) Evaluate the relative merits of your syntheses on the basis of selectivity and efficiency. (Decide which ones could be argued to be the "best" syntheses and which might be "poorer" syntheses.)
1. (a) Write as many chemically reasonable syntheses as you can think of for ethyl 2-methylpropyl ether (ethyl isobutyl ether). Be sure that at some point in one or more of your syntheses you utilize the following reagents (not all in the same synthesis, however): PBR3, SOCI2, p- toluenesulfonyl chloride (tosyl chloride), NaH, ethanol, 2-methyl-1-propanol (isobutyl alcohol), concentrated H2SO4, Hg(OAc)2, ethene (ethylene). (b) Evaluate the relative merits of your syntheses on the basis of selectivity and efficiency. (Decide which ones could be argued to be the "best" syntheses and which might be "poorer" syntheses.)
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Just asnwer part (b).
Transcribed Image Text:1. (a) Write as many chemically reasonable syntheses as you can think of for ethyl 2-methylpropyl ether (ethyl isobutyl ether). Be sure that
at some point in one or more of your syntheses you utilize the following reagents (not all in the same synthesis, however): PBr3, SOCI2, p-
toluenesulfonyl chloride (tosyl chloride), NaH, ethanol, 2-methyl-1-propanol (isobutyl alcohol), concentrated H2SO4, Hg(OAc)2, ethene
(ethylene).
(b) Evaluate the relative merits of your syntheses on the basis of selectivity and efficiency. (Decide which ones could be argued to be the
"best" syntheses and which might be "poorer" syntheses.)
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Synthesis of ethyl isobutyl ether using PBr3, SOCl2, and TsCl, NaOH, Na2SO4 etc and relative merits of synthesis on the basis of selectivity and efficiency has to be given.
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