. The reaction of an aryl amine with nitrite in the presence of perchlorate produces a diazonium salt. The initial rate of this reaction was measured using UV spectrometry at 25°C, at fixed initial concentrations of the aryl amine and perchlorate, but varying the initial concentration of nitrite. 0.06 0.04 0.02 0.01 [nitrite]o/ mol dm-3 Initial rate/ 108 mol dm-3 S-1 39.0 18.0 5.0 1.5 Using the table of data show that the reaction proceeds according to the rate law rate = k₁[nitrite]+ k₂[nitrite]² and calculate values for the rate constants.

. The reaction of an aryl amine with nitrite in the presence of perchlorate produces a diazonium salt. The initial rate of this reaction was measured using UV spectrometry at 25°C, at fixed initial concentrations of the aryl amine and perchlorate, but varying the initial concentration of nitrite. 0.06 0.04 0.02 0.01 [nitrite]o/ mol dm-3 Initial rate/ 108 mol dm-3 S-1 39.0 18.0 5.0 1.5 Using the table of data show that the reaction proceeds according to the rate law rate = k₁[nitrite]+ k₂[nitrite]² and calculate values for the rate constants.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter7: Alkynes

Section: Chapter Questions

Problem 7.19P

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