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Clo2 Residual Testing Method

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CHLORINE DIOXIDE AND CHLORITE

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7. ANALYTICAL METHODS
The purpose of this chapter is to describe the analytical methods that are available for detecting, measuring, and/or monitoring chlorine dioxide and chlorite, its metabolites, and other biomarkers of exposure and effect to chlorine dioxide and chlorite. The intent is not to provide an exhaustive list of analytical methods. Rather, the intention is to identify well-established methods that are used as the standard methods of analysis. Many of the analytical methods used for environmental samples are the methods approved by federal agencies and organizations such as EPA and the National Institute for Occupational Safety and Health (NIOSH). Other methods presented in this chapter …show more content…

The absorbance is proportional to the concentration of the chlorine dioxide in water. Indicators used for this technique include N,N-diethyl-p-phenylenediamine, chlorophenol red, and methylene blue (APHA 1998; Fletcher and Hemming 1985; Quentel et al. 1994; Sweetin et al. 1996). For example, chlorophenol red selectively reacts with chlorine dioxide at pH 7 with a detection limit of 0.12 mg/L. The interferences from chlorine may be reduced by the addition of oxalic acid, sodium cyclamate, or thioacetamide (Sweetin et al. 1996). APHA Method 4500-CLO2-B, iodometric titration analysis, measures the concentration of chlorine dioxide in water by titration with iodide, which is reduced to form iodine. Iodine is then measured colorimetrically when a blue color forms from the production of a starch-iodine complex. The detection limit for this method is 20 µg/L (APHA 1998).

CHLORINE DIOXIDE AND CHLORITE 7. ANALYTICAL METHODS

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Table 7-1. Analytical Methods for Determining Chlorine Dioxide and Chlorite in Environmental Samples
Sample matrix Preparation method
Air Workplace air None.

Analytical method
Toxic gas vapor detector tube

Sample Percent detection limit recovery Reference
0.05 ppm No data EPA 1997 Björkholm et al. 1990; Hekmat et al. 1994 (OSHA Method 202) Hoehn et al. 2000 (EPA Method 300.0) Pfaff and Brockhoff 1990 No data APHA 1998 (Method 4500CLO2-D)

Diffusion of air into potasIon chromatosium iodide solution at pH 7. graphy (of chlorite ion

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